130645-57-7

Upstream product

• 100-39-0 benzyl bromide 
• 3323-72-6 ethyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythrohex-2-enopyranoside 
• 80516-25-2 ethyl 2,3-dideoxy-6-O-benzyl-α-D-erythro-hex-2-enopyranoside 
• 23339-15-3 ethyl 2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 151807-90-8 ethyl 4-O-benzoyl-6-O-benzyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside 

Downstream Products

• 871584-84-8 ethyl 6-O-benzyl-4-O-trifluoroacetyl-2,3-dideoxyhex-2-enopyranoside 
• 871584-83-7 ethyl 6-O-benzyl-4-O-(ethylcarbonate)-2,3-dideoxyhex-2-enopyranoside 

Relevant academic research and scientific papers

A new route to 2-C- And 4-C-branched sugars by palladium-indium bromide-mediated carbonyl allylation

Palladium-catalysed carbonyl allylations can be effectively applied to the regio- and diastereoselective synthesis of 2-C- and 4-C-branched sugars from allylic esters or carbonates via the formation of π-allylpalladium(II) intermediates and their reductiv

Silylmethylene radical cyclization. A stereoselective approach to branched sugars

Ethyl 6-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside (2) was converted, in three steps and in 73percent overall yield, into ethyl 6-O-benzyl-2,3-dideoxy-3-C-(hydroxymethyl)-α-D-ribo-hex-2-enopyranoside.This transformation involved silylation of 2