80516-25-2

Upstream product

• 100-39-0 benzyl bromide 
• 23339-15-3 ethyl 2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 792908-44-2 6-O-benzyl-D-gulal 
• 792908-46-4 3-O-(t-butyldimethylsilyl)-4-O-mesyl-6-O-benzyl-D-gulal 
• 792908-45-3 3-O-(t-butyldimethylsilyl)-6-O-benzyl-D-gulal 
• 557793-03-0 6-O-(benzyl)-4-O-mesyl-D-glucal 
• 3323-72-6 ethyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythrohex-2-enopyranoside 

Downstream Products

• 142041-74-5 ethyl 2,3-dideoxy-6-O-benzyl-4-O-(2-benzothiazolyl)-α-D-erythro-hex-2-enopyranoside 
• 130619-57-7 2-((2R,3R,6S)-2-Benzyloxymethyl-6-ethoxy-3,6-dihydro-2H-pyran-3-ylsulfanyl)-benzothiazole 
• 151807-90-8 ethyl 4-O-benzoyl-6-O-benzyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside 
• 116235-33-7 (2R,3S,6S)-2-Benzyloxymethyl-6-ethoxy-3-methoxy-3,6-dihydro-2H-pyran 
• 871584-81-5 ethyl 6-O-benzyl-4-O-(ethylcarbonate)-2,3-dideoxyhex-2-enopyranoside 
• 871584-79-1 ethyl 4-O-acetyl-6-O-benzyl-2,3-dideoxyhex-2-enopyranoside 
• 871584-80-4 ethyl 4-O-benzoyl-6-O-benzyl-2,3-dideoxyhex-2-enopyranoside 
• 871584-82-6 ethyl 6-O-benzyl-4-O-trifluoroacetyl-2,3-dideoxyhex-2-enopyranoside 
• 130641-42-8 ethyl 2,3,4-trideoxy-2-C-n-butyl-6-O-benzyl-α-D-threo-hex-3-enopyranoside 
• 142041-75-6 ethyl 2,3,4-trideoxy-2-C-n-butyl-6-O-benzyl-α-D-erythro-hex-3-enopyranoside 
• 142041-76-7 ethyl 2,3,4-trideoxy-2-C-isopropyl-6-O-benzyl-α-D-erythro-hex-3-enopyranoside 
• 142041-72-3 ethyl 2,3,4-trideoxy-2-C-isopropyl-6-O-benzyl-α-D-threo-hex-3-enopyranoside 
• 142041-73-4 ethyl 2,3,4-trideoxy-2-C-phenyl-6-O-benzyl-α-D-threo-hex-3-enopyranoside 
• 116235-34-8 (5S,6R)-6-Benzyloxymethyl-5-methoxy-5,6-dihydro-pyran-2-one 

Relevant academic research and scientific papers

A new route to 2-C- And 4-C-branched sugars by palladium-indium bromide-mediated carbonyl allylation

Palladium-catalysed carbonyl allylations can be effectively applied to the regio- and diastereoselective synthesis of 2-C- and 4-C-branched sugars from allylic esters or carbonates via the formation of π-allylpalladium(II) intermediates and their reductiv

Stereospecific uncatalyzed α-O-glycosylation and α-C- glycosidation by means of a new D-gulal-derived α vinyl oxirane

The reaction of α vinyl oxirane 5, prepared through a new route to the D-gulal system, with O-nucleophiles (alcohols and di-O-isopropylidene- α-D-monosaccharides) and C-nucleophiles (lithium alkyls) affords, in a completely stereoselective way, the corres

Silylmethylene radical cyclization. A stereoselective approach to branched sugars

Ethyl 6-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside (2) was converted, in three steps and in 73percent overall yield, into ethyl 6-O-benzyl-2,3-dideoxy-3-C-(hydroxymethyl)-α-D-ribo-hex-2-enopyranoside.This transformation involved silylation of 2

A Straightforward Synthesis of L-Lactones from D-Glucose. A Simple Entry into L-Sugars

A new synthesis of 2,3-dideoxy-L-threo-hex-2-enono-1,5-lactones, starting from D-glucose, is described.