130659-40-4Relevant academic research and scientific papers
Hydroalumination of thioacetylenes: A versatile generation and reactions of α-aluminate sulfides intermediates
Guerrero Jr.,Dabdoub,Marques,Wosch,Baroni,Ferreira
experimental part, p. 4379 - 4394 (2009/04/11)
Hydroalumination of thioacetylenes using DIBAL-H and lithium di-(isobutyl)-n-(butyl)-aluminate hydride (Zweifel's reagent), followed by addition of water, furnished exclusively the (Z)- and (E)-vinyl sulfides, respectively. The regio- and stereochemistry
Stereoselective construction and synthetic applications of phenylthio substituted iodoolefins
Magriotis,Doyle,Kim
, p. 2541 - 2544 (2007/10/02)
(E)- and (Z)-Phenylthio substituted iodoolefins 1 and 2 have been synthesized stereoselectively via lower order stannylcuprate addition to and hydroalumination of appropriate alkyne precursors. Their utility in model studies on the synthesis of calichemic
