13070-22-9Relevant academic research and scientific papers
Synthetic method for N-substituent-3-aminoacrolein
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Paragraph 0027; 0038; 0039; 0040, (2017/08/29)
The invention discloses a synthetic method for N-substituent-3-aminoacrolein. The method comprises the following steps: with secondary amine and 3-chloroallyl alcohol as raw materials, and active manganese dioxide as a catalyst, carrying out introducing into an air environment, then carrying out a reaction at 0.5 to 2.5 MPa and 40 to 90 DEG C for 6 to 14 h, and after completion of the reaction, postprocessing a reaction solution so as to obtain an N-substituent-3-aminoacrolein derivative, wherein the yield is 68% to 97%. Compared with a conventional method for synthesizing the N-substituent-3-aminoacrolein, the method provided by the invention has the advantages of low toxicity, low pollution, simple operation, etc.
Gold-catalyzed heterogeneous aerobic dehydrogenative amination of α,β-unsaturated aldehydes to enaminals
Jin, Xiongjie,Yamaguchi, Kazuya,Mizuno, Noritaka
supporting information, p. 455 - 458 (2014/01/23)
Although enaminals (β-enaminals) are very important compounds and have been utilized as useful synthons for various important compounds, they have been synthesized through non-green and/or limited procedures until now. Herein, we have successfully develop
