130700-09-3Relevant academic research and scientific papers
Entry to β-alkoxyacrylates via gold-catalyzed intermolecular coupling of alkynoates and allylic ethers
Park, Sae Rom,Kim, Cheoljae,Kim, Dong-Gil,Thrimurtulu, Neetipalli,Yeom, Hyun-Suk,Jun, Jungho,Shin, Seunghoon,Rhee, Young Ho
, p. 1166 - 1169 (2013/05/09)
The first gold-catalyzed intermolecular coupling of alkynoates and allylic ethers invoking alkoxy addition and [3,3]-sigmatropic rearrangement as the key mechanism has been developed. Remarkably, the reaction showed complete chemoselectivity toward the pathway initiated by the alkoxy addition to alkynes. This unprecedented reactivity led to a new access to diversely substituted β-alkoxyacrylates in a highly efficient manner.
Palladium-Catalyzed Cross-Coupling of Aryl Halides and Olefinic Epoxides via Palladium Migration
Larock, Richard C.,Leung, Wai-Yee
, p. 6244 - 6245 (2007/10/02)
The palladium-catalyzed cross-coupling of aryl halides and olefinic epoxides bearing one to ten carbons between the two functional groups afford good yields of arylated allylic alcohols by a palladium migration process.
