130741-49-0Relevant academic research and scientific papers
STUDIES ON TUMOR PROMOTERS. 10. SYNTHESIS OF THE ABC RING SYSTEM OF THE TIGLIANES AND DAPHNANES BY A ZIRCONIUM-MEDIATED INTRAMOLECULAR ENYNE CARBOCYCLIZATION
Wender, Paul A.,McDonald, Frank E.
, p. 3691 - 3694 (1990)
A novel synthetic route to the ABC ring system of the daphnanes and tiglianes based on intramolecular enyne carbocyclization is described that provides access to a new family of diterpene tumor promotor analogs.
HYDROXY GROUP-ASSISTED ISOMERIZATION AND ALKYLATION OF ALLYLSILANES IN BASIC MEDIA. α-(1-TRIMETHYLSILYLALLYL) KETONE AS AN α-ALKENYL KETONE EQUIVALENT
Urabe, Hirokazu,Kuwajima, Isao
, p. 4241 - 4244 (2007/10/02)
Regioselective protonation and alkylation of a certain hydroxyallylsilane have been effected in basic media.An application of these reactions to a facile preparation of 3-hydroxy-1,5-hexadiene systems has also been achieved.
