130780-31-3Relevant academic research and scientific papers
C-Arylglycosylation of Unprotected Free Sugar
Toshima, Kazunobu,Matsuo, Goh,Ishizuka, Toru,Nakata, Masaya,Kinoshita, Mitsuhiro
, p. 1641 - 1642 (1992)
Highly regio- and stereo-selective C-arylglycosylations of the protected free sugars 1-4, the unprotected methyl glycosides 6-9 and the unprotected free sugars 10 and 11 with 2-naphthol 5 are effectively realized by the combined use of TMSOTf-AgClO4 (TMSO
Improvement in O -> C Glycoside Rearrangement Approach to C-Aryl Glycosides: Use of 1-O-Acetyl Sugar as Stable but Efficient Glycosyl Donor
Matsumoto, Takashi,Hosoya, Takamitsu,Suzuki, Keisuke
, p. 4629 - 4632 (2007/10/02)
1-O-Acetyl sugars serve as efficient glycosyl donor in the O -> C-glycoside rearrangement approach to C-aryl glycosides.Model study was carried out on three types of 2-deoxy-glycosyl acetates including amino sugar derivative.Comparison of the promoters, Cp2HfCl2-AgClO4, SnCl4, BF3*OEt2 is described.
