1309645-91-7Relevant academic research and scientific papers
Synthesis of Z-alkenyl phosphorus compounds through hydroalumination and carbocupration of alkynyl precursors
Ortial, Stephanie,Montchamp, Jean-Luc
supporting information; experimental part, p. 3134 - 3137 (2011/07/31)
The stereocontrolled synthesis of Z-alkenylphosphine-borane complexes is easily accomplished via the hydroalumination or carbocupration of alkynyl precursors. Z/E ratios are generally higher than 95/5. These reactions are stereocomplementary to our olefination approach.
