1309976-99-5

Upstream product

• 72223-17-7 1-trimethylsilyloxy-1,2-diphenylethylene 
• 1266134-54-6 2-azido-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium hexafluorophosphate (V) 
• 451-40-1 phenyl benzyl ketone 

Downstream Products

• 4695-13-0 2,2-diphenylacetamide 

Relevant academic research and scientific papers

Synthesis of α-Arylcarboxylic acid amides from silyl enol ether via migratory Amidation with 2-azido-1,3-dimethylimidazolinium hexafluorophosphate

α-Arylcarboxylic acid amides were synthesized by reacting silyl enol ethers of aryl ketones and 2-azido-1,3-dimethylimidazolinium hexafluorophosphate (ADMP,1). Silyl enol ethers react with ADMP 1 to give N-(α-arylacyl) guanidines via the migration of aryl groups in enol ethers. The products were transformed to the corresponding α-aryl acetamides by treating with LiAlH4.

Synthesis of α,α-diarylacetamides from benzyl aryl ketones using 2-azido-1,3-dimethylimidazolinium hexafluorophosphate

Benzyl aryl ketones reacted with 2-azido-1,3-dimethylimidazolinium hexafluorophosphate (ADMP, 1) to give migratory amidated compounds, which were transformed into the corresponding diarylacetamides by treating with LiAlH 4.