72223-17-7

Basic information

• Product Name: 1-trimethylsilyloxy-1,2-diphenylethylene
• Synonyms: 1-trimethylsilyloxy-1,2-diphenylethylene
• CAS NO: 72223-17-7
• Molecular Weight: 268.431
• Mol File: 72223-17-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-trimethylsilyloxy-1,2-diphenylethylene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-trimethylsilyloxy-1,2-diphenylethylene(72223-17-7)
• EPA Substance Registry System: 1-trimethylsilyloxy-1,2-diphenylethylene(72223-17-7)

Safety Data

• Hazardous Substances Data: 72223-17-7(Hazardous Substances Data)

Upstream product

• 451-40-1 phenyl benzyl ketone 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 143088-25-9 Selenophosphoric acid O,O'-diisopropyl ester Se-(2-oxo-1,2-diphenyl-ethyl) ester 
• 63578-71-2 Thiophosphoric acid O,O'-diethyl ester S-(2-oxo-1,2-diphenyl-ethyl) ester 
• 103422-99-7 2-<((benzyloxy)carbonyl)oxy>-1,2-diphenylethanone 
• 118621-73-1 2-(3,4-Dihydroxy-phenyl)-1,2-diphenyl-ethanone 
• 118621-81-1 5-tert-Butyl-2,3-diphenyl-benzofuran-7-ol 
• 118621-80-0 2-(2-tert-Butyl-4,5-dihydroxy-phenyl)-1,2-diphenyl-ethanone 
• 420-56-4 trimethylsilyl fluoride 
• 720-43-4 2-fluoro-1,2-diphenylethanone 
• 41848-64-0 3-bromo-1,2-diphenylpropan-1-one 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 1309976-99-5 C₁₉H₂₁N₃O 
• 108774-24-9 (2S*,3R*)-2,3-diphenylbutan-1-ol 
• 4441-01-4 1,2,4-triphenylbutane-1,4-dione 
• 365-01-5 2,2-difluoro-2-phenylacetophenone 

Relevant articles and documents

Alkyl Ethers as Traceless Hydride Donors in Br?nsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer

A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Br?nsted acid catalysis has been developed. The method is based on the use of either a benzyl or isopropyl ether as a traceless hydrogen-atom donor, and involves an intramolecular hydride transfer as a key step, which is achieved in a regio- and stereoselective manner.

Carbon-Carbon Bond Formation by the Use of Chloroiodomethane as a C1 Unit. III. A Convenient Synthesis of the Mannich Base from Enol Silyl Ether by a Combination of Chloroiodomethane and N,N,N',N'-Tetramethylmethanediamine

The Mannich dimethylaminomethylation of carbonyl compounds is conveniently carried out via enol trimethylsilyl ethers by a combination of chloroiodomethane (CH2ClI) and N,N,N',N'-tetramethylmethanediamine (TMMD) in DMSO as the solvent at ambient temperatute.The mechanism of the transformation is discussed on the basis of product analysis and 1H NMR spectral studies.The reagent system CH2ClI/TMMD also provides a convenient route to the Eschenmoser's salt ().