1310024-89-5

Upstream product

• 621-59-0 isovanillin 
• 10272-07-8 3.5-dimethoxyaniline 
• 25245-27-6 1-iodo-3,5-dimethoxybenzene 
• 14049-05-9 3-deoxy-1,2;5,6-di-O-isopropylidene-3-fluoro-α-D-glucofuranose 
• 1310024-88-4 (3-hydroxy-5-iodophenyl) 2,4,6-tri-O-acetyl-3-deoxy-3-fluoro-β-D-glucopyranoside 
• 621-58-9 3-hydroxy-4-methoxystyrene 
• 139200-04-7 2,4,6-tri-O-acetyl-3-deoxy-3-fluoro-α-D-glucopyranosylbromide 
• 64339-43-1 5-iodoresorcinol 

Relevant academic research and scientific papers

A short synthesis of rhaponticin and its 3''-fluoroanalog via a wittig/heck-mizoroki route

Rhaponticin and its 3''-fluoroanalog have been prepared from easily accessible starting materials. The key step of these syntheses is the silver carbonate-mediated glycosidation reaction employed for the selective formation of a β -glycosidic bond. A palladium acetate-catalyzed Heck-Mizoroki reaction in triethanolamine established an (E) configuration in the stilbene with simultaneous deprotection of the carbohydrate.