1310050-38-4Relevant academic research and scientific papers
4,6-Di-O-Benzylidenyl group-directed preparation of 2-deoxy-2-azido-α-D-galactopyranosides promoted by 3-O-TBDPS
Liang, Xing-Yong,Yang, Jing,Qiu, Zhong-Hao,Wang, Lei,Lowary, Todd L.,Shawn Fan, Hua-Jun
, (2021/02/06)
In this study, we designed a method to prepare 2-deoxy-2-azido-α-D-galactopyranosidic bonds using 4,6-di-O-benzylidenyl-3-O-t-butyldiphenylsilyl protected 2-deoxy-2-azido-1-thio-D-galactopyranoside 5 as donors. The donor 5 gives a good to excellent α-sele
Sub-stoichiometric reductive etherification of carbohydrate substrates and one-pot protecting group manipulation
Chen, Chiao Wen,Li, Xin Ru,Mong, Kwok-Kong Tony,Wang, Ching Chi,Witek, Henryk
, p. 3135 - 3141 (2020/05/08)
In this study, we report a new reductive etherification procedure for protection of carbohydrate substrates and its application for one-pot preparation of glycosyl building blocks. The reported procedure features the use of polymethylhydrosiloxane (PMHS)
Study of the stereoselectivity of 2-azido-2-deoxygalactosyl donors: Remote protecting group effects and temperature dependency
Kalikanda, Jane,Li, Zhitao
experimental part, p. 5207 - 5218 (2011/08/09)
The stereoselectivity of glycosylation reactions is affected by many factors. Synthesis of 1,2-cis glycosidic linkages (such as α linkages in glucose and galactose like monosaccharides) is challenging due to lack of control of the stereoselectivity. Our s
