13114-07-3Relevant academic research and scientific papers
C-P bond formation of cyclophanyl-, and aryl halides: Via a UV-induced photo Arbuzov reaction: A versatile portal to phosphonate-grafted scaffolds
Br?se, Stefan,Hassan, Zahid,Nieger, Martin,O?wald, Simon,Zippel, Christoph
, p. 3309 - 3312 (2022/02/11)
A new versatile method for the C-P bond formation of (hetero)aryl halides with trimethyl phosphite via a UV-induced photo-Arbuzov reaction, accessing diverse phosphonate-grafted arenes, heteroarenes and co-facially stacked cyclophanes under mild reaction
Cu2O/TiO2 nanoparticles as visible light photocatalysts concerning C(sp2)-P bond formation
Hosseini-Sarvari, Mona,Jafari, Fattaneh,Mohajeri, Afshan,Hassani, Nasim
, p. 4044 - 4051 (2018/08/24)
A novel and efficient method has been developed for the construction of an aromatic-phosphorus (Ar-P) bond under visible light irradiation using Cu2O/TiO2 nanoparticles as inexpensive and available photocatalysts. This protocol is a simple system without the use of any base, ligand, oxidant, or special conditions. This is the first report for the synthesis of arylphosphonates from arylhydrazines in visible light irradiation.
Copper-catalyzed coupling reaction of arylhydrazines and trialkylphosphites
Chen, Sheng-Yan,Zeng, Run-Sheng,Zou, Jian-Ping,Asekun, Olayinka Taiwo
, p. 1449 - 1453 (2014/03/21)
A novel CuO-catalyzed coupling reaction of arylhydrazines with trialkyl phosphites to afford arylphosphonates is described. The reaction proceeded at 80 C in air without external reductants, oxidants, and ligands.
A facile route to vinyl- and arylphosphonates by vinyl and aryl radical trapping with (MeO)3P
Jiao, Xian-Yun,Bentrude, Wesley G.
, p. 3303 - 3306 (2007/10/03)
The generation of vinyl or aryl radicals under classical, thermal AIBN/n-Bu3SnH conditions at 80 °C in the presence of an excess of (MeO)3P gives rise to the corresponding vinyl- or arylphosphonates in good yields. This approach comp
Palladium-Catalyzed Phase-Transfer Arylation of Dialkyl Phosphonates
Kabachnik,Solntseva,Izmer,Novikova,Beletskaya
, p. 93 - 97 (2007/10/03)
Palladium-catalyzed phase-transfer arylation of dialkyl phosphonates with various iodo- and bromoarenes has been studied. The arylation has also been effected in the absence of ligand. A simple preparative procedure for synthesizing arylphosphonic acids has been developed.
