131141-45-2Relevant academic research and scientific papers
LEWIS ACID MEDIATED REACTION OF SELENOACETALS WITH ALLYLSILANES AND ALLYLSTANNANES: SYNTHESIS OF HOMOALLYLSELENIDES
Hermans, Bernard,Hevesi, Laszlo
, p. 257 - 262 (2007/10/02)
Selenoacetals react with allyltrimethylsilane in the presence of tin tetrachloride to produce homoallyl selenides in moderate to good yields.Aliphatic acetals react less efficiently than do aromatic ones, especially when steric factors can play a signific
Regioselective syntheses of polycyclic compounds by carbanion-mediated polycyclisation of olefins
Krief,Barbeaux
, p. 417 - 420 (2007/10/02)
This paper reports straightforward syntheses of 1-aryl-bicyclo-[n. 1.0]-alkanes, 1-aryl-bicyclo-[3.3.0]-alkanes and of 1-phenyl-1,4-dimethyl-cyclopentane from unsaturated benzylselenides which involve the organolithiums-mediated cyclisation of olefins and
The reaction of allyltrimethylsilane with selenium-stabilized carbon electrophiles
Hermans, Bernard,Hevesi, Laszlo
, p. 4363 - 4366 (2007/10/02)
Lewis acid activation of bis(methylseleno)alcanes makes them react with allylsilane to produce the corresponding homoallyl selenides in moderate to good yields, depending on the structure of the starting selenoacetals.
