94417-53-5

Upstream product

• 6486-05-1 methyl selenide 
• 98-86-2 acetophenone 
• 94417-52-4 (Bis-methylselanyl-methyl)-benzene 
• 74-88-4 methyl iodide 
• 100-52-7 benzaldehyde 

Downstream Products

• 94417-58-0 2-(1-Methylselanyl-1-phenyl-ethyl)-cyclohexanone 
• 32773-42-5 butyl methyl selenide 
• 105824-54-2 1,2-diphenyl-2-methylseleno-propane-1-ol 
• 35342-70-2 4-methyl-4-phenyl-1,6-heptadiene 
• 131141-45-2 2-methylseleno-2-phenyl-4-pentene 
• 98369-90-5 <1-methyl-1-(methylseleno)ethyl>benzene 
• 162382-77-6 (E)-7-methylseleno-7-phenyl-2-octene 
• 162382-81-2 2-methyl-7-methylseleno-7-phenyl-2-octene 
• 162382-78-7 (Z)-7-methylseleno-7-phenyl-2-octene 
• 113328-02-2 6-methylseleno-6-phenylhept-1-ene 
• 113328-07-7 7-methylseleno-7-phenyloct-1-ene 
• 221347-54-2 (1E)-1-(2,3,5,6-tetramethylphenylthio)-6-methylseleno-6-phenylhept-1-ene 
• 104388-17-2 (1,2-Dimethyl-1-propyl-butyl)-benzene 
• 104388-16-1 (1-Methyl-1-propyl-heptyl)-benzene 

Relevant academic research and scientific papers

Regioselective syntheses of polycyclic compounds by carbanion-mediated polycyclisation of olefins

This paper reports straightforward syntheses of 1-aryl-bicyclo-[n. 1.0]-alkanes, 1-aryl-bicyclo-[3.3.0]-alkanes and of 1-phenyl-1,4-dimethyl-cyclopentane from unsaturated benzylselenides which involve the organolithiums-mediated cyclisation of olefins and

METALLATION OF BENZYL SELENIDES AND OF α-ARYL SELENOACETALS. SCOPE AND LIMITATIONS.

α-Metallo benzylselenides and α-metallo selenoacetals derived from aromatic aldehydes have been conveniently prepared by metallation of the corresponding carbon acids.KDA in THF proved among the various basic systems tested, the most efficient.

A NOVEL METHOD FOR THE GEMINAL DIALKYLATION OF THE CARBONYL GROUP OF AROMATIC ALDEHYDES AND KETONES

The title transformation is efficiently achieved by using the selenium methodology which involves the sequential reductive alkylation of arylselenoacetals and of benzylselenides.

SYNTHESIS OF SELENOACETALS

This paper reports our results concerning the syntheses of various bis(alkylseleno)alkanes and some of their arylseleno analogues by different methods.The scope and limitation of each of them are presented.