1313514-04-3Relevant articles and documents
Copper-mediated fluoroalkylation reactions with [(phenylsulfonyl)- difluoromethyl]trimethylsilane: Synthesis of PhSO2CF 2-containing allenes and alkynes
Zhu, Jieming,Wang, Fei,Huang, Weizhou,Zhao, Yanchuan,Ye, Wenchao,Hu, Jinbo
supporting information; experimental part, p. 899 - 902 (2011/06/19)
Copper-mediated (phenylsulfonyl)difluoromethylation of propargyl chlorides and alkynyl halides with PhSO2CF2TMS reagent was successfully achieved to give PhSO2CF2-containing allenes and alkynes, respectively. It is believed that the in situ formed PhSO 2CF2Cu species is involved in the present (phenylsulfonyl)difluoromethylation reactions. Georg Thieme Verlag Stuttgart · New York.