131379-56-1

Basic information

• Product Name: Propanenitrile, 3-[2,2,2-trimethyl-1,1-bis(trimethylsilyl)disilanyl]-
• CAS NO: 131379-56-1
• Molecular Formula: C12H31NSi4
• Molecular Weight: 301.727
• Mol File: 131379-56-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Propanenitrile, 3-[2,2,2-trimethyl-1,1-bis(trimethylsilyl)disilanyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Propanenitrile, 3-[2,2,2-trimethyl-1,1-bis(trimethylsilyl)disilanyl]-(131379-56-1)
• EPA Substance Registry System: Propanenitrile, 3-[2,2,2-trimethyl-1,1-bis(trimethylsilyl)disilanyl]-(131379-56-1)

Safety Data

• Hazardous Substances Data: 131379-56-1(Hazardous Substances Data)

Upstream product

• 626-62-0 Cyclohexyl iodide 
• 1873-77-4 tris-(trimethylsilyl)silane 
• 931-53-3 Cyclohexyl isocyanide 
• 107-13-1 acrylonitrile 
• 109797-66-2 decyl isocyanide 
• 119072-55-8 tert-butylisonitrile 
• 41320-40-5 <<(methylthio)thiocarbonyl>oxy>cyclohexane 
• 22233-91-6 phenylselenocyclohexane 

Downstream Products

• 109-78-4 3-Hydroxypropionitrile 

Relevant articles and documents

Tris(trimethylsilyl)silane as a Radical-Based Reducing Agent in Synthesis

Tris(trimethylsilyl)silane is an effective reducing agent for organic halides, selenides, xanthates, and isocyanides, as well as an effective hydrosilylating agent for dialkyl ketones and alkenes.The silane functions as a mediator in the formation of intermolecular carbon-carbon bonds via radicals and allows a variety of organic substrates to be used as alkyl radical precursors.Absolute rate constants for the reaction of (Me3Si)3Si* radicals with a variety of organic compounds have been measured in solution by laser flash photolysis.At 294 K rate constants are >5 x 107 M-1 s-1 for C=C double bonds that are activated by neighboring ?-electron systems or by electron-withdrawing groups.For other substrates, reactivities decreased in the order xanthate > selenide > isocyanide > nitro > sulfide.