131444-84-3

Upstream product

• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 137945-76-7 (R)-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl][(4S,5R)-5-ethenyl-2,2-dimethyl-1,3-dioxolan-4-yl]methanol 
• 131444-71-8 2-deoxy-3,4:6,7-di-O-isopropylidene-5-O-pivaloyl-D-manno-heptonic acid 
• 131444-70-7 1,2-dideoxy-3,4:6,7-di-O-isopropylidene-5-O-pivaloyl-D-manno-hept-1-enitol 
• 137945-80-3 2-deoxy-3,4:6,7-di-O-isopropylidene-5-O-pivaloyl-D-manno-heptitol 
• 3282-30-2 pivaloyl chloride 
• 7757-38-2 2,3,5,6-di-O-isopropylidene-D-mannofuranose 
• 131456-52-5 (methyl 2,3,4-tri-O-benzyl-α-D-glucopyranosid-6-yl) 2-deoxy-3,4:6,7-di-O-isopropylidene-5-O-pivaloyl-D-manno-heptonate 

Downstream Products

• 131444-88-7 methyl (1-O-acetyl-3-deoxy-4,5:7,8-di-O-isopropylidene-α-D-manno-octulopyranosyl)-(2->6)-(2,3,4-tri-O-benzyl-α-D-glucopyranoside) 
• 131444-89-8 methyl O-(methyl 3-deoxy-4,5:7,8-di-O-isopropylidene-α-D-manno-2-octulopyranosonate)-(2->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 137945-88-1 methyl (3-deoxy-4,5:7,8-di-O-isopropylidene-α-D-manno-octulopyranosyl)-(2->6)-(2,3,4-tri-O-benzyl-α-D-glucopyranoside) 
• 131444-86-5 methyl (1,3-dideoxy-1-iodo-4,5:7,8-di-O-isopropylidene-α-D-manno-octulopyranosyl)-(2->6)-(2,3,4-tri-O-benzyl-α-D-glucopyranoside) 
• 131444-90-1 methyl (methyl 3-deoxy-α-D-manno-octulosonate)-(2->6)-(2,3,4-tri-O-benzyl-α-D-glucopyranoside) 
• 131465-47-9 1,3-dideoxy-4,5:7,8-di-O-isopropylidene-2-O-(methyl 2,3,4-tri-O-benzyl-α-D-glucopyranosid-6-yl)-D-manno-oct-1-enitol 

Relevant academic research and scientific papers

Cyclization of Hydroxy Enol Ethers: A Stereocontrolled Approach to 3-Deoxy-D-manno-2-octulosonic Acid Containing Disaccharides

A method for the preparation of the carboxylic acids 14 and 15 has been developed, starting from known 2,3,5,6-di-O-isopropylidene-D-mannofuranose.Esterification of 14 and 15 with methanol, methyl 2,3,4-tri-O-benzyl-α-D-glucopyranoside, and 1,2,5,6-di-O-i

A STEREOCONTROLLED APPROACH TO 3-DEOXY-D-MANNO-2-OCTULOSONIC ACID CONTAINING DISACCHARIDES

The development of a synthetic approach to KDO containing disaccharides based on stereocontrolled iodocyclization of an enol ether is detailed.