131447-00-2Relevant academic research and scientific papers
Enantioselective allylic etherification: Selective coupling of two unactivated alcohols
Roggen, Markus,Carreira, Erick M.
supporting information; experimental part, p. 5568 - 5571 (2011/08/05)
An Ir(P,alkene) complex catalyzes the enantioselective allylic etherification of unactivated secondary allylic alcohols. Useful levels of enantioselectivity and yield were achieved with this operationally easy and robust protocol. Initial kinetic studies indicate a significant rate difference for the substrate enantiomers, allowing for a resolution process. cod=1,5-cyclooctadiene Copyright
Total Synthesis of (+)-Monomorine I via Nitrone Cycloaddition Route
Ito, Masayuki,Kibayashi, Chihiro
, p. 9329 - 9350 (2007/10/02)
An enantioselective total synthesis of (+)-monomorine I (1) is described.The key feature of the synthesis is the asymmetric 1,3-dipolar cycloaddition of the prochiral nitrone 9 with the chiral (S)-allylic ether 8 as a dipolarophile, which provides stereos
An alternative enantioselective total synthesis of (+)-monomorine I
Ito,Kibayashi
, p. 5065 - 5068 (2007/10/02)
An alternative enantioselective total synthesis of (+)-monomorine I has been achieved, based on asymmetric nitrone cycloaddition using a chiral allyl ether.
