131446-96-3

Upstream product

• 333788-78-6 (2S,3S)-2-Benzyloxy-3-(1-methoxy-1-methyl-ethoxy)-butane-1,4-diol 
• 333788-77-5 (2R,3R)-2-Benzyloxy-3-(1-methoxy-1-methyl-ethoxy)-succinic acid diethyl ester 
• 119770-87-5 (2R,3R)-diethyl 2-(benzyloxy)-3-hydroxysuccinate 

Downstream Products

• 131446-97-4 <4S,4(1S)>-4-<1-(Benzyloxy)pentyl>-2,2-dimethyl-1,3-dioxolane 
• 334793-69-0 (S)-4-((S)-1-Benzyloxy-propyl)-2,2-dimethyl-[1,3]dioxolane 
• 900783-31-5 4-[1-benzyloxy-(1S)-heptyl]-2,2-dimethyl-(4S)-1,3-dioxolane 
• 131447-01-3 methyl <3S,5R,5(1S)>-N-benzyl-5-<1-(benzyloxy)pentyl>isoxazolidine-3-carboxylate 
• 138890-28-5 (6S,8R,9S)-6-(Dibenzylamino)-9-(benzyloxy)-2,2-ethylenedioxy-8-hydroxytridecane 
• 138890-26-3 <4S,6R,6(1S)>-N-Benzyl-6-<1-(benzyloxy)pentyl>-4-<(4,4-ethylenedioxy)pentyl>-3,4,5,6-tetrahydro-1,3-oxazin-2-one 
• 138890-29-6 (6S,8R,9S)-6-(Dibenzylamino)-9-(benzyloxy)-8-hydroxytridecan-2-one 
• 138890-25-2 <4S,6R,6(1S)>-N-Benzyl-6-<1-(benzyloxy)pentyl>-4-(4-oxopentyl)-3,4,5,6-tetrahydro-1,3-oxazin-2-one 
• 138890-24-1 <4S,6R,6(1S)>-N-Benzyl-6-<1(benzyloxy)pentyl>-4-(4-pentenyl)-3,4,5,6-tetrahydro-1,3-oxazin-2-one 
• 138890-27-4 (6S,8R,9S)-6-(Benzylamino)-9-(benzyloxy)-2,2-ethylenedioxy-8-hydroxytridecane 
• 138890-30-9 <2S,2(2R),2(3S),6S>-2-<3-(Benzyloxy)-2-hydroxyheptyl>-6-methylpiperidine 
• 131447-02-4 methyl <3S,5S,5(1S)>-N-benzyl-5-<1-(benzyloxy)pentyl>isoxazolidine-3-carboxylate 
• 131447-01-3 methyl <3R,5R,5(1S)>-N-benzyl-5-<1-(benzyloxy)pentyl>isoxazolidine-3-carboxylate 
• 131447-07-9 (6S,8R,9S)-6-amino>-9-benzyloxy-8-<(benzyloxy)carbonyl>oxytridecan-2-one 

Relevant academic research and scientific papers

The first total synthesis of (+)-rogioloxepane A

The first total synthesis of (+)-rogioloxepane A is described. The α,ω-trans-disubstituted oxepene skeleton was stereoselectively constructed via cyclization of the hydroxy epoxide promoted by the (Bu3Sn)2O/Zn(OTf)2 system. The proposed configurations of 6R and 13R were confirmed through this synthetic study.