1314568-55-2Relevant academic research and scientific papers
Convenient access to the tricyanoborate dianion B(CN)32- and selected reactions as a boron-centred nucleophile
Landmann, Johannes,Sprenger, Jan A. P.,Bertermann, Rüdiger,Ignat'Ev, Nikolai,Bernhardt-Pitchougina, Vera,Bernhardt, Eduard,Willner, Helge,Finze, Maik
, p. 4989 - 4992 (2015)
Alkali metal tricyanoborates M2B(CN)3 (M = Na, K) are accessible by the reaction of tricyanofluoroborates with alkali metals (i) in liquid NH3 or (ii) in THF-naphthalene. The M2B(CN)3 are versatile starting materials for the synthesis of K[RB(CN)3] (R = Et, C6F5, CH2CHCH2).
PROCESS FOR THE PREPARATION OF PERFLUOROALKYLCYANO- OR PERFLUOROALKYLCYANOFLUOROBORATES
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Page/Page column 15-16, (2012/12/14)
The invention relates to a process for the preparation of salts having perfluoroalkyltricyano- or perfluoroalkylcyanofluoroborate anions, ((per)fluoro)phenyltricyano- or ((per)fluoro)phenylcyanofluoroborate anions, phenyltricyanoborate anions which are mo
