13150-75-9

Basic information

• Product Name: N-(dimethyl-lambda~4~-sulfanylidene)-4-methylbenzenesulfonamide
• CAS NO: 13150-75-9
• Molecular Formula: C₉H₁₃NO₂S₂
• Molecular Weight: 231.335
• Mol File: 13150-75-9.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 389.4°C at 760 mmHg
• Flash Point: 189.3°C
• Density: 1.26g/cm³
• Vapor Pressure: 6.4E-06mmHg at 25°C
• Refractive Index: 1.587
• CAS DataBase Reference: N-(dimethyl-lambda~4~-sulfanylidene)-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(dimethyl-lambda~4~-sulfanylidene)-4-methylbenzenesulfonamide(13150-75-9)
• EPA Substance Registry System: N-(dimethyl-lambda~4~-sulfanylidene)-4-methylbenzenesulfonamide(13150-75-9)

Safety Data

• Hazardous Substances Data: 13150-75-9(Hazardous Substances Data)

Usage

General Description

N-(dimethyl-lambda~4~-sulfanylidene)-4-methylbenzenesulfonamide is a chemical compound with the molecular formula C9H12N2O2S2. It is a sulfonamide derivative, containing a sulfanylidene group attached to a benzene ring, along with dimethyl and methyl substituents. N-(dimethyl-lambda~4~-sulfanylidene)-4-methylbenzenesulfonamide has several potential applications, including as a pharmaceutical intermediate, a chemical reagent, and a building block for organic synthesis. It may also have biological activity and could potentially be used in medicinal chemistry research. The precise properties and uses of this compound would depend on its specific chemical behavior and interactions.

Upstream product

• 75-18-3 dimethylsulfide 
• 70284-20-7 N-bromo-N-potassio-p-toluenesulfonamide 
• 67-68-5 dimethyl sulfoxide 
• 207804-83-9 N-acryloyl-N-methyl-N'-p-tolylsulfonylurea 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 103-19-5 di(p-tolyl) disulfide 
• 1593-60-8 p-toluenesulfonylhydroxylamine 
• 33840-97-0 (toluene-4-sulfonyl)-imidosulfurous acid dichloride 
• 120263-52-7 N'-tosyl-N-(trimethylsilyl)sulfur diimide 
• 70841-00-8 dibutyl di(p-methylphenyl)tin 
• 937-12-2 4-tolyltrimethylstannane 
• 4083-64-1 Tosyl isocyanate 
• 127-65-1 chloroamine-T 
• 120263-51-6 1,7-bis(tosyl) trisulfur tetranitride 

Downstream Products

• 22236-45-9 S,S-dimethyl-N-(4-tolylsulfonyl)sulfoximine 
• 75-18-3 dimethylsulfide 
• 70-55-3 toluene-4-sulfonamide 
• 882-33-7 diphenyldisulfane 
• 67869-02-7 2,3,5-Trimethyl-6-methylthiomethyl-phenol 
• 18738-36-8 2-methoxy-6-methylthiomethylphenol 
• 67869-01-6 3,5-Dimethyl-6-methylthiomethyl-phenol 
• 5485-71-2 N-(2-bromo-1-phenylethyl)-4-methylbenzenesulfonamide 
• 4626-23-7 3,6-Dimethyl-2-thiomethoxymethyl-phenol 

Relevant articles and documents

Copper-catalyzed imination of sulfoxides and sulfides

Sulfoximines and sulfilimines have attracted considerable interest among organic chemists. The Cu(II)-catalyzed imination of sulfoxides and sulfides using various N-fluoro benzenesulfonamides was investigated in this study. The scope of the reaction was demonstrated by using several substituted sulfides and sulfoxides. The flow strategy for the preparation of NH-sulfoximines was also examined. By trapping nitrene intermediates through triphenylphosphine, we found that the reaction was conducted through a metal-nitrene intermediate mechanism.

Highly efficient sulfimidation of 1,3-dithianes by Cu(I) complexes

A series of four Cu(I) complexes were tested for sulfimidation of 1,3-dithianes in the presence of [N-(p-tolysulfonyl)imino]phenyliodinane (PhI=NTs) as the nitrene-transfer agent. Cu(TMPhen)(PPh3)Br is an efficient catalyst with more than 90% yield of the