131509-99-4

Basic information

• Product Name: 3-(methylthio)-4-phenyl-1,2-butadiene
• Synonyms: 3-(methylthio)-4-phenyl-1,2-butadiene
• CAS NO: 131509-99-4
• Molecular Weight: 176.282
• Mol File: 131509-99-4.mol

Chemical Properties

• CAS DataBase Reference: 3-(methylthio)-4-phenyl-1,2-butadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(methylthio)-4-phenyl-1,2-butadiene(131509-99-4)
• EPA Substance Registry System: 3-(methylthio)-4-phenyl-1,2-butadiene(131509-99-4)

Safety Data

• Hazardous Substances Data: 131509-99-4(Hazardous Substances Data)

Upstream product

• 22174-51-2 1-methylthio-1-propyne 
• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 

Downstream Products

• 131510-09-3 (E)-N-benzyl-1-isopropyl-2-methylene-3-methylthio-4-phenyl-3-butenylamine 
• 131510-08-2 (Z)-N-benzyl-1-isopropyl-2-methylene-3-methylthio-4-phenyl-3-butenylamine 
• 131510-13-9 (E)-N-benzyl-1-(1-methylene-2-methylthio-3-phenyl-2-propenyl)pentylamine 
• 131510-12-8 (Z)-N-benzyl-1-(1-methylene-2-methylthio-3-phenyl-2-propenyl)pentylamine 
• 131510-11-7 (E)-N-benzyl-2-methylene-3-methylthio-1,4-diphenyl-3-butenylamine 
• 131510-10-6 (Z)-N-benzyl-2-methylene-3-methylthio-1,4-diphenyl-3-butenylamine 
• 144937-98-4 (E)-1-cyclohexyl-2-methylene-3-methylthio-4-phenyl-3-buten-1-ol 
• 131541-94-1 (Z)-1-cyclohexyl-2-methylene-3-methylthio-4-phenyl-3-buten-1-ol 
• 131541-91-8 (Z)-2-methylene-3-methylthio-1,4-diphenyl-3-buten-1-ol 
• 131510-18-4 (E)-2-methylene-3-methylthio-1,4-diphenyl-3-buten-1-ol 
• 132118-93-5 methyl 3-benzyl-4-methylene-3-(methylthio)-2-((2-oxo-1,3-oxazolidin-3-yl)carbonyl)cyclobutanecarboxylate 
• 132118-93-5 (1R,3R,4S)-3-Benzyl-2-methylene-3-methylsulfanyl-4-(2-oxo-oxazolidine-3-carbonyl)-cyclobutanecarboxylic acid methyl ester 
• 145212-53-9 (1S,3R,4R)-3-Benzyl-2-methylene-3-methylsulfanyl-4-(2-oxo-oxazolidine-3-carbonyl)-cyclobutanecarboxylic acid methyl ester 
• 145212-61-9 (1S,3S,4R)-3-Benzyl-2-methylene-3-methylsulfanyl-4-(2-oxo-oxazolidine-3-carbonyl)-cyclobutanecarboxylic acid methyl ester 

Relevant articles and documents

Asymmetric [2 + 2] cycloaddition reaction catalyzed by a chiral titanium reagent

In the presence of certain Lewis acids, alkenes containing an alkylthio group (for example, ketene dithioacetals, alkenyl sulfides, alkynyl sulfides, and allenyl sulfides) react with electron deficient olefins to give the corresponding cyclobutane, cyclobutene, or methylene cyclobutane derivatives. By employing a chiral titanium catalyst generated in situ from dichlorodiisopropoxytitanium and a tartrate-derived chiral diol, the [2 + 2] cycloaddition reaction proceeds with high enantioselectivity.

Ene Reaction of Allenyl Sulfides with Aldehydes and Schiff's Bases Catalyzed by Lewis Acids

Ene reaction proceeds between α-alkyallenyl sulfides and enophiles such as aldehydes and Schiff's bases in the presence of Lewis acid to afford various 1,3-dienes.