13154-31-9

Basic information

• Product Name: 2-NITROCYCLODODECANONE
• Synonyms: 2-NITROCYCLODODECANONE
• CAS NO: 13154-31-9
• Molecular Formula: C₁₂H₂₁NO₃
• Molecular Weight: 227.3
• Product Categories: C11 to C12;Carbonyl Compounds;Ketones
• Mol File: 13154-31-9.mol
• Article Data: 6

Chemical Properties

• Melting Point: 77-80 °C(lit.)
• Boiling Point: 366.2 °C at 760 mmHg
• Flash Point: 164.1 °C
• Appearance: /
• Density: 1.04g/cm³
• Vapor Pressure: 1.48E-05mmHg at 25°C
• Refractive Index: 1.477
• CAS DataBase Reference: 2-NITROCYCLODODECANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-NITROCYCLODODECANONE(13154-31-9)
• EPA Substance Registry System: 2-NITROCYCLODODECANONE(13154-31-9)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 13154-31-9(Hazardous Substances Data)

Usage

General Description

2-NITROCYCLODODECANONE is a nitro-containing cyclic ketone that is commonly used as a fuel additive and in the production of various chemical compounds. It is a pale yellow liquid with a slightly fruity odor and is highly flammable. 2-NITROCYCLODODECANONE is known to have irritant and toxic effects on the skin and eyes, and is also harmful if swallowed or inhaled. It is important to handle this chemical with caution and use proper protective equipment when working with it. Additionally, 2-NITROCYCLODODECANONE is classified as a hazardous substance and should be stored, handled, and disposed of in accordance with all relevant regulations and guidelines.

InChI:InChI=1/C12H21NO3/c14-12-10-8-6-4-2-1-3-5-7-9-11(12)13(15)16/h11H,1-10H2

Upstream product

• 1129-89-1 cis-cyclododecene 
• 32399-66-9 Essigsaeure-(1-cyclododecenyl)ester 
• 71365-98-5 1-Acetoxy-cis-cyclododecen 
• 830-13-7 cyclododecanone 

Downstream Products

• 32571-74-7 12-nitrododecanoic acid 
• 1731-79-9 dodecanedioic acid dimethyl ester 
• 52190-43-9 2-(phenylthio)cyclododecan-1-one 
• 693-23-2 1,12-dodecanedioic acid 
• 86572-33-0 benzyl 3-oxo-5-(1-nitro-2-oxocyclododecyl)pentanoate 

Relevant articles and documents

Practical and User-Friendly Procedure for Michael Reactions of α-Nitroketones in Water

A variety of α,β-unsaturated carbonyl derivatives gave selective Michael additions with several α-nitrocycloalkanones in water, at room temperature without any added catalyst, or in very dilute, aqueous solutions of potassium carbonate. Both preparative methods constitute new, environmentally benign and more efficient alternatives to previous procedures.

Syntheses of macrocyclic lactones by ring enlargement reaction. Preparation of (±)-phoracantholide I, (±)-dihydrorecifeiolide and (±)-15-hexadecanolide

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Synthese von N-(4-Aminobutyl)-16-aza-19-nonadecanlactam und N-(4-Aminobutyl)-17-aza-20-icosanlactam (Desoxoinandenin)

According to Scheme 1, the two homologous macrocyclic spermidine derivatives 12 ad 23 were synthesized.Key steps in both cases were two different types of ring-enlargement reactions.Compound 12 was identical with a degradation product of the naturally occurring spermidine akaloids of inandine-type.