1315575-48-4Relevant academic research and scientific papers
Ni-Catalyzed direct 1,4-difunctionalization of [60]fullerene with benzyl bromides
Si, Weili,Zhang, Xuan,Asao, Naoki,Yamamoto, Yoshinori,Jin, Tienan
supporting information, p. 6392 - 6394 (2015/04/14)
A new Ni-catalyzed direct 1,4-difunctionalization of [60]fullerene with various benzyl bromides has been developed. The use of a DMSO additive combined with a nickel catalyst is indispensable for the formation of 1,4-dibenzyl fullerenes with a variety of
Cu-catalyzed C-H amination of Hydrofullerenes leading to 1,4-Difunctionalized Fullerenes
Si, Weili,Lu, Shirong,Bao, Ming,Asao, Naoki,Yamamoto, Yoshinori,Jin, Tienan
supporting information, p. 620 - 623 (2014/04/03)
A novel and highly efficient Cu-catalyzed C-H amination of the monofunctionalized hydrofullerenes for the synthesis of 1,4-difunctional fullerenes has been reported. A new series of 1,4-fullerene derivatives having various monoamine addends were synthesized in good to high yields under mild reaction conditions. The controlled experiments revealed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate followed by coupling with an amine radical.
NaOH-catalyzed dimerization of monofunctionalized hydrofullerenes: Transition-metal-free, general, and efficient synthesis of single-bonded [60]fullerene dimers
Lu, Shirong,Jin, Tienan,Bao, Ming,Yamamoto, Yoshinori
supporting information; experimental part, p. 3466 - 3469 (2012/09/07)
Unprecedented, transition-metal-free NaOH-catalyzed homo- and cross-dimerizations of monofunctionalized hydrofullerenes are reported. Various single-bonded fullerene dimers were synthesized under mild reaction conditions with remarkably high yields. The u
