13160-55-9

Upstream product

• 90-02-8 salicylaldehyde 
• 108-42-9 3-chloro-aniline 
• 886-32-8 m-chlorophenylsalicylaldimine 
• 886-32-8 (E)-2-((3-chlorophenylimino)methyl)phenol 

Downstream Products

• 1258930-29-8 2-chloro-N-(2-hydroxybenzyl)-N-(3-chlorophenyl)acetamide 
• 1260217-93-3 C₂₃H₂₃BrClN₂O₂P 
• 1260217-92-2 C₂₁H₁₉BrClN₂O₂P 
• 1260217-91-1 C₂₃H₂₃Cl₂N₂O₂P 
• 1260217-90-0 N-[2-(4-chlorophenoxy)-3-(3-chlorophenyl)-3,4-dihydro-2H-1,3,2-λ5-benzoxazaphosphinin-2-yliden]-N-allyl amine 
• 1260217-89-7 C₂₆H₂₀Cl₂N₃O₄P 
• 1260217-88-6 C₂₂H₂₁Cl₂N₂O₂P 
• 1260217-87-5 C₂₃H₂₃Cl₂N₂O₂P 
• 1260217-86-4 C₂₁H₁₉Cl₂N₂O₂P 

Relevant academic research and scientific papers

Metal-Free Diaryl Etherification of Tertiary Amines by Ortho-C(sp2)-H Functionalization for Synthesis of Dibenzoxazepines and -ones

A phenyliodine(III) diacetate mediated umpolung reactivity of the tertiary amines with suitably substituted o-hydroxybenzyl and phenyl groups is exploited to facilitate o-C(sp2)-H functionalization to afford diaryl ethers. The presence of an o-

Palladium-Catalyzed Regioselective C-Benzylation via a Rearrangement Reaction: Access to Benzyl-Substituted Anilines

An unprecedented C-benzylation rearrangement reaction, catalyzed by palladium, is reported. The reaction proceeds by rearrangement leading to the direct synthesis of para or ortho benzyl-substituted N-methylanilines. The product is obtained in high regioselectivity, without the need to use a ligand for the catalytic process.

Synthesis and structure-antibacterial activity relationship studies of 4-substituted phenyl-4,5-dihydrobenzo[f][1,4]oxazepin-3(2H)-thiones

The synthesis and characterization of a series of 4-substituted phenyl-4,5-dihydrobenzo[f][1,4]oxazepin- 3(2H)-thiones were presented. Preliminary in vitro antimicrobial activity of the compounds was assessed against a panel of microorganisms including S.

Synthesis and spectral characterization of N-[2-(4-halophenoxy)-3-(3- chlorophenyl)-3, 4-dihydro-2H-1,3,2-Λ5-benzoxazaphosphinin-2- yliden]-N-substituted amines by the Staudinger reaction

The synthesis of the title compounds was accomplished in four steps. The synthetic route involves the preparation of Schiff's base by reacting salicylaldehyde with m-chloroaniline in EtOH. The Schiff's base was then reduced with NaBH4/MeOH. In the second step, PCl3 was reacted with p-chlorophenol/p-bromophenol in THF in the presence of Et3N to obtain P(III) dichloride derivatives. The reduced Schiff's base and dichloride derivatives were reacted in equimolar quantities in the presence of Et 3N in THF to get the cyclized product. Alkyl azides were prepared by reacting alkyl bromides with sodium azide, and then alkyl azides were treated with the cyclized product to obtain the title compounds. The structure of these novel compounds was elucidated by elemental analysis, IR, 1H, 13C, 31P NMR, and mass spectroscopy.

Zirconium borohydride - A versatile reducing agent for the reduction of electrophilic and nucleophilic substrates

Zirconium borohydride, a potential reducing agent, reduces acids, esters, imines to the corresponding alcohols and secondary amines in good yield at room temperature within two hours. This facile reducing property was taken advantage off in the synthesis of pheromones and some novel chiral precursors for asymmetric synthesis.