886-32-8

Basic information

• Product Name: N-(3-Chlorophenyl)-2-hydroxybenzenemethaneimine
• Synonyms: 2-(3-Chlorophenyliminomethyl)phenol;2-[[(3-Chlorophenyl)imino]methyl]phenol;3-Chloro-N-(2-hydroxybenzylidene)aniline;N-(3-Chlorophenyl)-2-hydroxybenzenemethaneimine;N-Salicylidene-3-chloroaniline
• CAS NO: 886-32-8
• Molecular Formula: C₁₃H₁₀ClNO
• Molecular Weight: 231.68
• Mol File: 886-32-8.mol
• Article Data: 14

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-(3-Chlorophenyl)-2-hydroxybenzenemethaneimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3-Chlorophenyl)-2-hydroxybenzenemethaneimine(886-32-8)
• EPA Substance Registry System: N-(3-Chlorophenyl)-2-hydroxybenzenemethaneimine(886-32-8)

Safety Data

• Hazardous Substances Data: 886-32-8(Hazardous Substances Data)

Upstream product

• 90-02-8 salicylaldehyde 
• 108-42-9 3-chloro-aniline 
• 89-95-2 2-methyl-benzyl alcohol 

Downstream Products

• 89-95-2 2-methyl-benzyl alcohol 
• 1360873-49-9 (3aS,4R,9aR)-N-(3-chlorophenyl)-3,3a,4,9a-tetrahydro-2H-furo[2,3-b]chromen-4-amine 
• 13160-55-9 N-(3-chlorophenyl)2-hydroxy benzylamine 
• 1222170-29-7 4-(3-chlorophenyl)-4,5-dihydrobenzo[f][1,4]oxazepin-3(2H)-thione 
• 1222170-18-4 4-(3-chlorophenyl)-4,5-dihydrobenzo[f][1,4]oxazepin-3(2H)-one 
• 1258930-29-8 2-chloro-N-(2-hydroxybenzyl)-N-(3-chlorophenyl)acetamide 
• 1322617-44-6 N-(3-benzyl-4-(3-chlorophenylamino)-2-oxochroman-3-yl)benzamide 
• 1322617-41-3 N-(3-benzyl-4-(3-chlorophenylamino)-2-oxochroman-3-yl)benzamide 
• 1260217-93-3 C₂₃H₂₃BrClN₂O₂P 
• 1260217-92-2 C₂₁H₁₉BrClN₂O₂P 
• 1260217-91-1 C₂₃H₂₃Cl₂N₂O₂P 
• 1260217-90-0 N-[2-(4-chlorophenoxy)-3-(3-chlorophenyl)-3,4-dihydro-2H-1,3,2-λ5-benzoxazaphosphinin-2-yliden]-N-allyl amine 
• 1260217-89-7 C₂₆H₂₀Cl₂N₃O₄P 
• 1260217-88-6 C₂₂H₂₁Cl₂N₂O₂P 

Relevant articles and documents

Effect of substituents on the UV spectra of supermolecular system: Silver nanoparticles with bi-aryl Schiff bases containing hydroxyl

Effect of substituents on the ultraviolet (UV) spectra of supermolecular system involving silver nanoparticles (AgNPs) and Schiff bases was investigated. AgNPs and 49 samples of model compounds (MC), bi-aryl Schiff bases containing hydroxyl (XBAY, involving 4-OHArCH?NArY, 2-OHArCH?NArY, XArCH?NAr-4′-OH, and XArCH?NAr-2′-OH), were synthesized. The size of AgNPs was characterized by transmission electron microscopy (TEM), and the UV absorption spectra of AgNPs, XBAYs, and MC-AgNPs mixed solutions were measured, respectively. The results show that (1) the size of AgNPs is larger in MC-AgNPs solutions than that in AgNPs solution due to the distribution of MC molecules on the surface of AgNPs; (2) the UV absorption wavelength of XBAYs changes in the action of AgNPs and their wavelength shift exists limitation between XBAY and MC-AgNPs solutions; and (3) the wavelength shift limit of MC-AgNPs (λWSL) is influenced by the substituents X and Y and the position of hydroxyl OH. The wavenumber ΔνWSL of λWSL can be quantified by employing the excited-state substituent constant σexCC and Hammett constant σ of substituents X and Y. Comparing with the 4-OH, the 4′-OH makes the ΔνWSL a red shift, whereas the 2′-OH, comparing with the 2-OH, makes the ΔνWSL a blue shift.

Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands

Treatment of the bidentate Schiff base 2-[(2,6-diisopropyl-phenylimino)-methyl]-phenol (HL1) with one equivalent of (Et4N)[RuCl4(MeCN)2] in the presence of triethylamine afforded (Et4N)[RuCl3(κ2

Halide substituted Schiff-bases: Different activities in methyltrioxorhenium(VII) catalyzed epoxidation via different substitution patterns

This report shows the influence of halide substituted Schiff-bases as ligands of methyltrioxorhenium (MTO) in epoxidation catalysis. Therefore, selected Schiff-bases were prepared by the reaction of hydroxy-benzaldehydes and aniline derivates. These differently substituted Schiff-bases were tested as MTO-ligands in cyclooctene-and 1-octene-epoxidation. Although no great disparities among the substitution patterns have been found, some conclusions can be drawn. Flourines are inferior to chlorines or bromines as substituents. Halides in ortho-position lead to higher activities than in para-or meta-position. The balance between electron donating and withdrawing influences at the Schiff-base plays a prominent role in their utility as ligand to MTO in epoxidation catalysis.