144693-97-0Relevant academic research and scientific papers
Remote Asymmetric Induction Based on Carbonyl-Ene Reactions with Bishomoallylic Silyl Ether: Dramatic Changeover of Regioselectivity by the Remarkable Siloxy Effect
Shimizu, Masaki,Mikami, Koichi
, p. 6105 - 6106 (1992)
A new approach to remote asymmetric induction is described for not only a 1,4- but also a 1,5-relationship, which is based on the carbonyl-ene reactions with chiral bishomoallylic silyl ethers.Silyl ethers, rather than alkyl ethers, exhibit β-regiospecifi
