131869-23-3Relevant academic research and scientific papers
Oxidative ring cleavage of cyclic acetals with hypervalent tert-butylperoxy-λ3-iodanes
Sueda, Takuya,Fukuda, Sonoko,Ochiai, Masahito
, p. 2387 - 2390 (2001)
(matrix presented) Exposure of cyclic acetals to 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in the presence of tert-butyl hydroperoxide and potassium carbonate in benzene at room temperature results in oxidative ring cleavage to glycol monoesters via intermediate tert-butylperoxy ortho esters.
Synthesis of tert-butyl peroxyacetals from benzyl, allyl, or propargyl ethers via iron-promoted C-H bond functionalization
Iwata, Satoshi,Hata, Takeshi,Urabe, Hirokazu
supporting information, p. 3480 - 3484 (2013/02/22)
When benzyl, allyl, and propargyl ethers were treated with tert-butyl hydroperoxide and a catalytic amount of iron(III) acetylacetonate, tert-butyl peroxyacetals were produced in good to excellent yields, via C-H bond functionalization. This method is also applicable to ethylene acetals of unsaturated aldehydes to give peroxyorthoesters.
