132047-89-3

Upstream product

• 99838-68-3 (2R,3S)-3-(benzyloxy)hex-5-ene-1,2-diol 
• 87604-58-8 (S)-(-)-2-Benzyloxypent-4-enal 
• 100-39-0 benzyl bromide 
• 79364-35-5 (S)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol 
• 87604-53-3 (R)-4-((S)-1-(benzyloxy)but-3-ene-1-yl)-2,2-dimethyl-1,3-dioxypentane 
• 75-77-4 chloro-trimethyl-silane 
• 112505-92-7 (S)-3-(benzyloxy)-1,1-dibromo-hexa-1,5-diene 

Downstream Products

• 132047-91-7 4(S)-(benzyloxy)-11-<(tert-butyldiphenylsilyl)oxy>-6-(trimethylsilyl)undeca-1,5,7-triene 
• 132047-95-1 5(S)-(benzyloxy)-12<(tert-butyldiphenylsilyl)oxy>-7-(trimethylsilyl)undeca-6,8-dienenitrile 
• 132048-01-2 7(S)-(benzyloxy)-14-<(tert-butyldiphenylsilyl)oxy>-2-methyl-9-(trimethylsilyl)tetradeca-2,8,10-trienal 
• 132047-97-3 methyl 7(S)-(benzyloxy)-14-<(tert-butyldiphenylsilyl)oxy>-2-methyl-9-(trimethylsilyl)tetradeca-2,8,10-trienoate 
• 132048-00-1 (2E,8Z,10E)-(S)-7-Benzyloxy-14-(tert-butyl-diphenyl-silanyloxy)-2-methyl-9-trimethylsilanyl-tetradeca-2,8,10-trien-1-ol 
• 112505-93-8 (E)-3(S)-(benzyloxy)-1-iodo-1-(trimethylsilyl)hexa-1,5-diene 

Relevant academic research and scientific papers

Enantioselective Synthesis of the Bottom Half of Chlorothricolide. 3. Studies of the Steric Directing Group Strategy for Stereocontrol in Intramolecular Diels-Alder Reactions

The intramolecular Diels-Alder reactions of a series of C(7)-alkoxy-substituted 2(E),8(Z),10(E)-undecatrienoates and trienals containing removable C(9)-Br or C(9)-SiMe3 substituents (11, 12, 13, 33, 42, 43, 44, 45) were studied as part of a programm direc

Enantioselective Synthesis of the Bottom Half of Chlorothricolide. 2. A Comparative Study of Substituent Effects on the Stereoselectivity of the Key Intramolecular Diels-Alder Reaction

The intramolecular Diels-Alder reactions of trienes 4-7 were studied to evaluate the ability of diene (TMS, Br) and dienophile (CHO, CO2Me) substituents to influence Diels-Alder stereoselectivity and thereby define the optimal precursor to the bottom half of chlorothricolide.