132203-71-5

Basic information

• Product Name: (+)-TRANS-MYRTANOL
• Synonyms: (1R,2R)-10-PINANOL;(1R,2R)-6,6-DIMETHYLBICYCLO[3.1.1]HEPTANE-2-METHANOL;(+)-TRANS-MYRTANOL;(+)-TRANS-MYRTANOL, TERPENE STANDARD;MYRTANOL, -(-)-trans-(SG);(1R,2R)-10-Pinanol, (1R,2R)-6,6-Dimethylbicyclo[3.1.1]heptane-2-methanol
• CAS NO: 132203-71-5
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.25
• EINECS: 258-499-8
• Mol File: 132203-71-5.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 219.5°C at 760 mmHg
• Flash Point: 86 °C
• Appearance: /
• Density: 0.973 g/mL at 20 °C(lit.)
• Vapor Pressure: 0.0249mmHg at 25°C
• Refractive Index: n20/D 1.488
• Storage Temp.: 2-8°C
• PKA: 14.99±0.10(Predicted)
• CAS DataBase Reference: (+)-TRANS-MYRTANOL(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-TRANS-MYRTANOL(132203-71-5)
• EPA Substance Registry System: (+)-TRANS-MYRTANOL(132203-71-5)

Safety Data

• Safety Statements: 23-24/25
• RIDADR: UN 1993 / PGIII
• WGK Germany: 3
• F: 10-23
• Hazardous Substances Data: 132203-71-5(Hazardous Substances Data)

Usage

General Description

(+)-TRANS-MYRTANOL is a naturally occurring fragrance chemical that is commonly used in the production of perfumes and other scented products. It is a colorless liquid with a sweet, floral, and woody odor and is often used to add a fresh and clean scent to various products. (+)-TRANS-MYRTANOL is known for its high stability and excellent fixative properties, which help to prolong the fragrance of the products in which it is used. It is also commonly found in essential oils and is considered to be safe for use in skincare and cosmetic products. Overall, (+)-TRANS-MYRTANOL is a versatile and popular fragrance ingredient known for its pleasant scent and ability to enhance the overall fragrance profile of many different products.

InChI:InChI=1/C10H18O/c1-10(2)8-4-3-7(6-11)9(10)5-8/h7-9,11H,3-6H2,1-2H3/t7-,8+,9+/m0/s1

Upstream product

• 23727-16-4 myrtenal 
• 6712-78-3 myrtenol 
• 1118071-19-4 2-chloromethyl-6,6-dimethylbicyclo[3.1.1]heptane 
• 127-91-3 (1R,5R)-(+)-β-pinene 
• 64-17-5 ethanol 
• 33741-31-0 (1R,2S)-pinan-10-oic acid methyl ester 
• 515-00-4 (+/-)-myrtenol 
• 127-91-3 (1R/S,5R/S)-6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane 
• 177698-19-0 Beta-pinene 
• 64-19-7 acetic acid 
• 33741-30-9 methyl (1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carboxylate 
• 18172-67-3 beta-pinene 
• 601-74-1 (1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carboxylic acid 

Downstream Products

• 4764-14-1 (+/-)-Myrtanal 
• 4764-14-1 (+/-)-Isomyrtanal 
• 29021-36-1 (1R)-10-Acetoxy-cis-pinan 
• 81510-28-3 (1R,2R,5R)-2-[2-(Diphenyl-phosphinoyl)-ethoxymethyl]-6,6-dimethyl-bicyclo[3.1.1]heptane 
• 127-92-4 6,6-Dimethyl-bicyclo<3.1.1>heptan 
• 590410-99-4 (1R,2R,5R)-trans-myrtanyl tosylate 
• 16750-96-2 trans-Myrtanyl-tosylat 
• 4764-14-1 (-)-cis-myrtanal 
• 81510-31-8 [2-((1R,2R,5R)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-ylmethoxy)-ethyl]-diphenyl-phosphane 
• 4764-14-1 cis-myrtanal 

Relevant articles and documents

Visible-Light-Mediated Aerobic Oxidation of Organoboron Compounds Using in Situ Generated Hydrogen Peroxide

A simple and general visible-light-mediated oxidation of organoboron compounds has been developed with rose bengal as the photocatalyst, substoichiometric Et3N as the electron donor, as well as air as the oxidant. This mild and metal-free protocol shows a broad substrate scope and provides a wide range of aliphatic alcohols and phenols in moderate to excellent yields. Notably, the robustness of this method is demonstrated on the stereospecific aerobic oxidation of organoboron compounds.

PS-COD and PS-9-BBN: Polymer-supported reagents for solution-phase parallel synthesis

(Chemical Equation Presented) 1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity to 9-BBN in olefin hydroboration.

METHOD OF HYDROBORATING ALCOHOLS AND REDUCING FUNCTIONAL GROUPS USING A RECYCLABLE FLUOROUS BORANE-SULFIDE

A method of hydroborating an alkene or alkyne, or reducing an organic functionality, oxidizing primary and secondary alcohols using a fluorous borane-sulfide is disclosed. The method includes regeneration and recycling the fluorous borane-sulfide.