Substrate-Controlled Diastereoselectivities in Catalyzed and Uncatalyzed Hydroborations of Acyclic Allylic Alcohol Derivatives: Secondary Orbital Effects Involving d?-p? Interactions

DOI: 10.1021/jo00003a023

Source and publish data:

Journal of Organic Chemistry p. 1020 - 1027 (1991)

Update date:2022-08-05

Topics:

Authors:

Burgess, Kevin

Cassidy, Juanita

Ohlmeyer, Michael J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00003a023

Rhodium-mediated hydroborations of allylic alcohol derivatives 1-9 followed by oxidation give predominantly syn-2-methyl 1,3-diols whereas conventional hydroborations of the same substrates afford mostly anti products.It is proposed that mixing of ?^*

Full text of DOI:10.1021/jo00003a023

Products guided by the article

Product name:2-methyl-1-(pentafluorophenyl)-2-propen-1-ol acetate

Cas No:132317-36-3

R&D Labs maybe for 132317-36-3

Landz International Company Ltd.

Contact:0086-21-58891610

Address:985 Dongfang Road, Pudong, Shanghai 200122 China
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China
Hefei EnliPharma Tecnology Co.,Ltd

Contact:0086-551-66399836

Address:Qing Cheng ShuiXiang Building 805, Mengcheng North Road , ShuangFeng Economic Development Zone Anhui HeFei
Chongqing Changfeng Chemical Co., Ltd.

website:http://www.changfengchem.com

Contact:+86-23-67896333

Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China

Relevant to this article

TWO ANTHOCHLOR PIGMENTS FROM HEARTWOOD OF PTEROCARPUS MARSUPIUM

Doi:10.1016/S0031-9422(00)98027-0
(1989)
Synthesis and pharmacological activities of some 3-substituted thienopyrimidin-4-one-2-thiones

Doi:10.1016/0223-5234(90)90128-P
(1990)
140. Acid-Catalyzed <3,3>-Sigmatropic Rearrangements of N-Propargylanilines

Doi:10.1002/hlca.19900730602
(1990)
Organometallic iridium(III) cyclopentadienyl anticancer complexes containing C,N-Chelating ligands

Doi:10.1021/om2005468
(2011)
Net heterolytic cleavage of B-H and B-B bonds across the N-Pd bond in a cationic (PNP)Pd fragment

Doi:10.1021/ic2001283
(2011)
Synthesis of 1,2,5- and 1,2,3,5-substituted pyrroles from substituted aziridines via Ag(I)-catalyzed intramolecular cyclization

Doi:10.1016/j.tet.2011.02.072
(2011)

Article Doi