Substrate-Controlled Diastereoselectivities in Catalyzed and Uncatalyzed Hydroborations of Acyclic Allylic Alcohol Derivatives: Secondary Orbital Effects Involving d?-p? Interactions

DOI: 10.1021/jo00003a023

Source and publish data:

Journal of Organic Chemistry p. 1020 - 1027 (1991)

Update date:2022-08-05

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Authors:

Burgess, Kevin

Cassidy, Juanita

Ohlmeyer, Michael J.

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Article abstract of DOI:10.1021/jo00003a023

Rhodium-mediated hydroborations of allylic alcohol derivatives 1-9 followed by oxidation give predominantly syn-2-methyl 1,3-diols whereas conventional hydroborations of the same substrates afford mostly anti products.It is proposed that mixing of ?^*

Full text of DOI:10.1021/jo00003a023

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