Journal of Organic Chemistry p. 1020 - 1027 (1991)
Update date:2022-08-05
Topics:
Burgess, Kevin
Cassidy, Juanita
Ohlmeyer, Michael J.
Rhodium-mediated hydroborations of allylic alcohol derivatives 1-9 followed by oxidation give predominantly syn-2-methyl 1,3-diols whereas conventional hydroborations of the same substrates afford mostly anti products.It is proposed that mixing of ?*
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