1323883-35-7

Basic information

• Product Name: C₁₅H₁₅ClN₂O
• Synonyms: C₁₅H₁₅ClN₂O
• CAS NO: 1323883-35-7
• Molecular Weight: 274.75
• Mol File: 1323883-35-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₅ClN₂O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₅ClN₂O(1323883-35-7)
• EPA Substance Registry System: C₁₅H₁₅ClN₂O(1323883-35-7)

Safety Data

• Hazardous Substances Data: 1323883-35-7(Hazardous Substances Data)

Upstream product

• 3173-56-6 benzyl isothiocyanate 
• 72024-59-0 S-(4-chlorophenyl) benzylcarbamothioate 
• 104-86-9 4-chlorobenzylamine 
• 51955-56-7 S-p-tolyl benzylcarbamothioate 
• 72024-41-0 S-phenyl benzylcarbamothioate 
• 1384678-89-0 p-bromophenyl N-benzylthiocarbamate 

Relevant articles and documents

Kinetics and mechanism of the aminolysis of aryl N-benzyl thiocarbamates in acetonitrile

The aminolysis reactions of phenyl N-benzyl thiocarbamate with benzylamines in acetonitrile at 50.0 °C are investigated. The reactions are first order in both the amine and the substrate. Under amine excess, pseudo-first coefficient (kobs) are obtained, plot of kobs vs free amine concentration are linear. The signs of ρXZ (X and ρZ with respect to the sustituent in the substrate and large ρXZ value indicate that the reactions proceed concerted mechanism. The normal kinetic isotope effects (kH/k D = 1.3 ～ 1.5) involving deuterated benzylamine nucleophiles suggest a hydrogen-bonded, four-centered-type transition state. The activation parameters, ΔH?and AS?, are consistent with this transition state structure.