72024-41-0

Basic information

• Product Name: S-phenyl benzylcarbamothioate
• CAS NO: 72024-41-0
• Molecular Formula: C₁₄H₁₃NOS
• Molecular Weight: 243.3241
• Mol File: 72024-41-0.mol
• Article Data: 10

Chemical Properties

• Density: 1.2g/cm³
• Refractive Index: 1.636
• CAS DataBase Reference: S-phenyl benzylcarbamothioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-phenyl benzylcarbamothioate(72024-41-0)
• EPA Substance Registry System: S-phenyl benzylcarbamothioate(72024-41-0)

Safety Data

• Hazardous Substances Data: 72024-41-0(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 88333-03-3 Benzyl isocyanide 
• 124-38-9 carbon dioxide 
• 108-98-5 thiophenol 
• 100-46-9 benzylamine 
• 108-86-1 bromobenzene 
• 19093-37-9 allyl phenyl sulfoxide 
• 220573-65-9 diethyl 2-(phenylsulfinyl)succinate 
• 55543-78-7 (+/-)-Methyl 3-(Phenylsulfinyl)propanoate 
• 62076-10-2 (tert-butylsulfinyl)benzene 
• 6343-54-0 N-benzylformamide 
• 42116-44-9 N-tert-butoxycarbonylbenzylamine 
• 39896-97-4 benzyl-carbamic acid benzyl ester 
• 1212-08-4 S-Phenyl benzenethiosulfonate 

Downstream Products

• 104385-10-6 N-benzyl-2,4,6-trimethylbenzamide 
• 882-33-7 diphenyldisulfane 
• 92277-82-2 N-Benzyl-N'-(4-methylbenzyl)urea 
• 108-98-5 thiophenol 
• 1466-67-7 1,3-dibenzylurea 
• 1323883-35-7 C₁₅H₁₅ClN₂O 

Relevant articles and documents

Synthesis of carbamothioate derivatives via a copper catalyzed thiocarboxamidation of aryl iodides

Abstract: A catalytic route to carbamothioate derivatives through a reaction involving isocyanides, elemental sulfur, and aryl iodides has been developed. The reaction scope has been examined using a range of isocyanides and aryl iodides. The reactions involve two consecutive C–S bond formations. Control experiment revealed that the reaction proceeds through an iminium species. Graphic abstract: [Figure not available: see fulltext.].

Thermolysis-Induced Two- or Multicomponent Tandem Reactions Involving Isocyanides and Sulfenic-Acid-Generating Sulfoxides: Access to Diverse Sulfur-Containing Functional Scaffolds

Direct reaction of isocyanides with some sulfenic-acid-generating sulfoxides led to the effective formation of the corresponding thiocarbamic acid S-esters in good to high yields. A multicomponent reaction involving isocyanide, sulfoxide, and a suitable nucleophile has also been developed, providing ready access to a diverse range of sulfur-containing compounds, including isothioureas, carbonimidothioic acid esters, and carboximidothioic acid esters.

One-pot synthesis of carbamates and thiocarbamates from Boc-protected amines

A highly efficient one-pot procedure for the synthesis of carbamates and thiocarbamates has been described. In the presence of 2-chloropyridine and trifluoromethanesulfonyl anhydride, the isocyanate intermediates were generated in situ for further reactions with alcohols and thiols to afford the desired carbamates and thiocarbamates in high yields.