132395-52-9Relevant academic research and scientific papers
On Triazoles. XXII. Synthesis of Dialkyl (3-Q-1,2,4-Triazol-5-yl)iminodithiocarbonates
Reiter, Jozsef,Pongo, Laszlo,Pallagi, Istvan
, p. 1689 - 1696 (2007/10/02)
Isomeric dialkyl and diaralkyliminodithiocarbonates 4a-c (R not equal H) were synthesised and their spectral data compared.The uv, cmr and ms rules elaborated helped to prove the tautomeric structure of the non-substituted derivatives 4 (R = H).In case of dimethyl (3-methylthio-1,2,4-triazol-5-yl)iminodithiocarbonate this is the first time ever crystalline triazole desmotropes 4a/17 and 4b/17 could be isolated.The sodium salts of 4 (R = H) could be further alkylated and aralkylated to yield the corresponding 4 (R = alkyl and aralkyl) type derivatives.Providing the above reaction in the presence of carbon disulfide the dithiocarbomethoxy derivative 7 was obtained.
