132398-29-9

Upstream product

• 49762-08-5 3-hydroxy-4-methylthiazole-2(3H)-thione 
• 132398-27-7 2-Methyl-2-benzyl-6-phenylthio-4-hexenoic acid chloride 
• 144898-89-5 Methyl 2-methyl-2-benzyl-6-bromo-4-hexenoate 
• 144898-97-5 Methyl 2-methyl-2-benzyl-6-phenylthio-4-hexenoate 
• 144899-02-5 2-Methyl-2-benzyl-6-phenylthio-4-hexenoic acid 
• 29393-16-6 methyl 2-methyl-3-phenylpropionate 

Downstream Products

• 132398-33-5 4-Methyl-4-benzyl-2-vinylcyclopentanenitrile 
• 132398-32-4 1-Methyl-1-benzyl-2-vinylcyclopropane 

Relevant academic research and scientific papers

Sequential Radical Addition/Cyclization/β-Elimination Reactions. 3-exo- and 5-exo-Cycloaddition Reactions of 5-Phenylthio-3-pentenyl and 5-Phenylthio-3-pentynyl Radicals

Sequential radical addition/5-exo-cyclization/β-elimination reactions, accomplished by thermally or photolytically induced decompositions of O-acyl derivatives of N-hydroxypyridine-2-thione or other thiohydroxamic esters of 6-phenylthio-4-hexenoic acids 1

RADICAL CYCLIZATION REACTIONS. CYCLOPROPANE RING FORMATION BY 3-EXO-CYCLIZATIONS OF 5-PHENYLTHIO-3-PENTENYL RADICALS

Free radical cyclopropane ring closure was accomplished by thermal decomposition of thiohydroxamic esters of 6-phenylthio-4-hexenic acids.When the reaction was performed in the presence of acrylonitrile, an addition/cyclization/elimination process took place and the corresponding cyclopentanecarbonitriles were obtained.