49762-08-5

Usage

Chemical Properties

green-brown to brown solid

InChI:InChI=1/C4H5NOS2/c1-3-2-8-4(7)5(3)6/h2,6H,1H3

Upstream product

• 49762-81-4 O-ethyl-S(2-oximinopropyl)dithiocarbonate 

Downstream Products

• 100780-10-7 3-cyclohexylcarboxy-4-methylthiazole-2(3H)-thione 
• 1222145-91-6 N-(4-nitrobenzoyl)-4-methylthiazole-2(3H)-thione 
• 1186242-72-7 N-[(S)-2-methoxy-2-phenylacetyloxy]-4-methylthiazole-2(3H)-thione 
• 1186242-73-8 N-[(R)-2-methoxy-2-phenylacetyloxy]-4-methylthiazole-2(3H)-thione 
• 1186242-70-5 (+/-)-N-(2-methoxy-2-phenylacetyloxy)-4-methylthiazole-2(3H)-thione 
• 228729-55-3 7-benzoyloxy-oxabicyclo[3.3.0]octan-3-one-6-carboxy-4-methylthiazole-2(3H)-thione 
• 131544-18-8 3-<(cyclohexylcarbamoyl)oxy>-4-methylthiazole-2(3H)-thione 
• 205492-63-3 6-Methyl-1-(4-methyl-2-thioxo-thiazol-3-yloxycarbonylmethyl)-2-oxo-cyclohex-3-enecarboxylic acid ethyl ester 
• 185981-08-2 1-(4-Methyl-2-thioxo-thiazol-3-yloxycarbonylmethyl)-2-oxo-cyclohexanecarboxylic acid ethyl ester 

Relevant academic research and scientific papers

Biocide composition and use

A method for the preservation of a plastics material against the growth of deteriogens which comprises treating the plastics material with a composition comprising a) an isothiazolin-3-one such as N-n-octyl- or 4,5-dichloro-N-n-octyl-isothiazolin-3-one and b) the metal complex of a thiohydroxamic acid such as 2:1 zinc complex of 3-hydroxy-4-methylthiazol-2(3H)-thione or the 2:1 zinc complex of 1-hydroxypyridine-2-thione.

Biocidal composition and its use

A composition comprising a C3-5-alkyl-1,2-benzisothiazolin-3-one and the metal complex of a cyclic thiohydroxamic acid such as the 2:1 zinc salt of either 3-hydroxy-4-methylthiazol-2(3H)-thione or 1-hydroxypyridine-2-thione.

Cyclopentane ring formation in the cycloaddition reaction of 3-alkenyl radicals to radicophilic olefins

Regioselective additions of 3-alkenyl radicals (10 and 20) to electron deficient olefinic bonds (7 and 17), followed by intramolecular 5- exo-cyclization and repeated addition to radicophilic double bonds were investigated and combined into a sequence of

The Invention of New Radical Chain Reactions. Part 9. Further Radical Chemistry of Thiohydroxamic Esters; Formation of Carbon-Carbon Bonds

Carbon radicals derived from the esters of several types of thiohydroxamic acids have been trapped in a number of different ways.Particular attention has been paid to carbon-carbon bond formation by addition to suitably activated ethylenic linkages.Carboxylic acids can be conveniently converted into homo- and bishomo-acids by free radical chemistry based on thiohydroxamic esters.In a coda the tautomerism of the thiohydroxamic acids have been examined by physical methods.It is confirmed that the esters used are derivatives of the thione tautomer.

RADICAL CHEMISTRY OF THIOHYDROXAMIC ACID ESTERS

Thiohydroxamic esters in general decompose smoothly by a radical chain reaction to give carbon radicals which can be quenched in a synthetically useful manner.