13243-58-8

Basic information

• Product Name: 2-Phenyl-1-oxaspiro<2.5>octan-4-on
• Synonyms: 2-Phenyl-1-oxaspiro<2.5>octan-4-on
• CAS NO: 13243-58-8
• Molecular Weight: 202.253
• Mol File: 13243-58-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-Phenyl-1-oxaspiro<2.5>octan-4-on(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Phenyl-1-oxaspiro<2.5>octan-4-on(13243-58-8)
• EPA Substance Registry System: 2-Phenyl-1-oxaspiro<2.5>octan-4-on(13243-58-8)

Safety Data

• Hazardous Substances Data: 13243-58-8(Hazardous Substances Data)

Upstream product

• 5682-83-7 (E)-2-benzylidenecyclohexanone 
• 5682-83-7 2-Benzylidenecyclohexanone 
• 100-52-7 benzaldehyde 
• 822-87-7 2-Chlorocyclohexanone 
• 1056477-06-5 2-bromocyclohexanone 
• 108-94-1 cyclohexanone 

Downstream Products

• 70388-68-0 4-(Z-Cyanmethylen)-2(E)-phenyl-1-oxaspiro<2,5>octan 
• 70388-68-0 4-(E-Cyanmethylen)-2(E)-phenyl-1-oxaspiro<2,5>octan 
• 70388-73-7 trans-2-Phenyl-2,3,4,5,6,7-hexahydrobenzofuran-3-carbonsaeure-methylester 
• 70388-73-7 cis-2-Phenyl-2,3,4,5,6,7-hexahydrobenzofuran-3-carbonsaeure-methylester 
• 70388-72-6 trans-2-Phenyl-2,3,4,5,6,7-hexahydrobenzofuran-3-carbonitril 
• 70388-72-6 cis-2-Phenyl-2,3,4,5,6,7-hexahydrobenzofuran-3-carbonitril 
• 18014-85-2 2-Phenyl-2,3,4,5,6,7-hexahydrobenzofuran 
• 100-52-7 benzaldehyde 
• 73920-94-2 4-Dicyanmethylen-2(E)-phenyl-1-oxaspiro<2,5>octan 
• 81357-84-8 trans-3-(2,3,4,5,6,7-Hexahydro-2-phenylbenzofuran-3-yl)-2-methyl-2-propensaeure-methylester 
• 81357-84-8 cis-3-(2,3,4,5,6,7-Hexahydro-2-phenylbenzofuran-3-yl)-2-methyl-2-propensaeure-methylester 
• 28008-96-0 3''-phenyl-3H-dispiro[benzothiazole-2,1'-cyclohexane-2',2''-oxirane] 
• 47185-17-1 phenyl-(1,2,3,4-tetrahydro-phenothiazin-4a-yl)-methanol 
• 73920-93-1 4-Methylen-2(E)-phenyl-1-oxaspiro<2,5>octan 

Relevant articles and documents

Epoxidation of Alkenes with Molecular Oxygen as the Oxidant in the Presence of Nano-Al 2O 3

The nano-Al 2O 3-promoted epoxidation of alkenes with molecular oxygen as the oxidant has been developed, providing an efficient route to a variety of epoxides in moderate to excellent yields. The environmentally friendly and efficient nano-Al 2O 3catalyst could be easily recovered and reused five times without significant loss of activity.

Stereodivergent Access to Enantioenriched Epoxy Alcohols with Three Stereogenic Centers via Ruthenium-Catalyzed Transfer Hydrogenation

The resolution technique of stereodivergent reaction on racemic mixtures (stereodivergent RRM) was employed for the first time in ruthenium complex catalyzed transfer hydrogenation of racemic epoxy ketones, providing a new and very simple method that allows access to enantioenriched epoxy alcohols with three stereogenic centers in a one-step fashion. The protocol features simple reaction conditions, practical operation, ability to scale up, and broad group tolerance.

Highly chemo- and regioselective rearrangement of α,β-epoxy ketones to 1,3-dicarbonyl compounds in 5 mol dm-3 lithium perchlorate-diethyl ether medium

Epoxides from α,β-unsaturated ketones undergo highly chemo- and regioselective rearrangement to 1,3-dicarbonyl compounds in 5 mol dm-3 lithium perchlorate-diethyl ether medium by a 1,2-migration of the carbonyl group at ambient conditions. The Royal Society of Chemistry 1999.