132431-16-4Relevant articles and documents
2-(N-Methylanilino)-2-phenylthioacetonitrile: a Useful Reagent for Preparation of Conjugated α-Amino Alkenenitriles via Tandem Alkylation and Dehydrosulphenylation
Fang, Jim-Min,Chen, Chih-Cheng
, p. 3365 - 3367 (2007/10/02)
Alkylation of the anion of 2-(N-methylanilino)-2-phenylthioacetonitrile 1 with halogenoalkanes resulted in concurrent elimination of benzenethiol to give conjugated α-aminoalkenenitriles of 2E-configuration.Counterattack by bromide and benzenethiolate ion