36602-08-1Relevant articles and documents
Chemistry of gold(III) with pyridine-carboxamide ligands
Nasser, Nasser,Puddephatt, Richard J.
, p. 61 - 67 (2014)
The pyridine-carboxamide ligand PhNHC(O)2-C5H4N reacts with Na+[AuCl4]- either by cation exchange, to give [PhNHC(O)2-C5H4NH][AuCl4], or by ligand substitution to give
Surface engineered Iridium-based magnetic photocatalyst paving a path towards visible light driven C-H arylation and cyanation reaction
Gaur, Rashmi,Gawande, Manoj B.,Kaushik, Bhawna,Rana, Pooja,Sharma, Priti,Sharma, Rakesh K.,Yadav, Priya,Yadav, Sneha
, p. 297 - 308 (2021/08/23)
The report presents the fabrication and application of a highly versatile, magnetic and robust iridium based photoredox nanocatalyst. Herein, Ir(PPy)3 based photocatalyst sites have been chemically engineered over the magnetic nanoparticles to encompass the captivating features of homogeneous iridium photocatalyst with the magnetically recyclable core. A household photoreactor was designed and fabricated to achieve highly selective visible light driven oxidative C-H arylation and C-H cyanation under sustainable and ambient reaction conditions utilizing the Ir@PyBz@ASMNPs photoredox nanocatalyst. The environment friendly Ir@PyBz@ASMNPs shows excellent photocatalytic activity, broad substrate adaptability and outstanding recyclability compared to the analogous homogeneous catalysts. Indeed, the Ir@PyBz@ASMNPs possess some key features including high surface area, high iridium metal loading and excellent stability. This work is expected to enlighten and provide new insights in the rational design of high performance and recoverable photoredox nanocatalyst through surface engineering strategy.
Synthesis method of alpha-cyanide
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Paragraph 0053-0054, (2021/08/19)
The invention relates to the field of synthesis of chemical products, in particular to a synthesis method of alpha-cyanide, the synthesis method comprises the following steps: starting from easily available tertiary amine compounds, respectively taking ch
