132552-99-9Relevant academic research and scientific papers
A new method for the synthesis of amides from imines
Ghaffarzadeh, Mohammad,Joghan, Somaye Shahrivari,Faraji, Fereshteh
experimental part, p. 203 - 206 (2012/03/07)
An efficient and straightforward method for the synthesis of amides by the reaction of imines and anhydrides in the presence of Et3SiH/Zn is reported. Mild reaction conditions, good yields of products, short reaction times, and operational simplicity are advantages of this procedure.
Synthesis of amides from imines using Et3SiH/Zn system
Ghaffarzadeh, Mohammad,Heidarifard, Somaye,Faraji, Fereshteh,Joghan, Somaye Shahrivari
experimental part, p. 103 - 107 (2012/05/05)
A simple and efficient approach for the synthesis of amides by the reaction of imines and acyl chlorides in the presence of Et3SiH/Zn system in THF at ambient temperature is reported. Mild reaction conditions, good yields of products, short reaction time and operational simplicity are the advantages of this procedure. Copyright
AROMATIC CYCLIZATIONS OF β-AMINOETHYL RADICALS AND α-CARBAMOYLMETHYL RADICALS. ORTHO-SUBSTITUTION VS. IPSO-SUBSTITUTION
Ishibashi, Hiroyuki,Nakamura, Nobuyuki,Ito, Katsuhiro,Kitayama, Shinji,Ikeda, Masazumi
, p. 1781 - 1784 (2007/10/02)
On being treated with Bu3SnH, the N-benzyl-N-(β-bromoethyl)sulfonamide (4) underwent a homolytic ortho-substitution reaction to give the tetrahydroisoquinoline (6).In contrast, the N-arylmethyl-α-chloroacetamides (10) afforded the ipso-substitution products (11).A similar treatment of the N-naphthylmethyl derivative (16) provided the spiro-γ-lactam (17).
