1326319-35-0Relevant academic research and scientific papers
Expanding the scope of Et3B/O2-mediated coupling reactions of O,Te-acetal
Kamimura, Daigo,Nagatomo, Masanori,Urabe, Daisuke,Inoue, Masayuki
, p. 7839 - 7848 (2016/11/17)
Et3B/O2-mediated radical coupling reactions of O,Te-acetal 2 were explored using diverse electrophilic double bonds. Ethyl radical derived from Et3B under air cleaved the C–Te bond of 2 to generate α-alkoxy bridgehead radi
Et3B-mediated radical-polar crossover reaction for single-step coupling of O,Te-acetal, α,β-unsaturated ketones, and aldehydes/ketones
Kamimura, Daigo,Urabe, Daisuke,Nagatomo, Masanori,Inoue, Masayuki
supporting information, p. 5122 - 5125 (2013/10/22)
Et3B-mediated three-component coupling reactions between O,Te-acetal, α,β-unsaturated ketones, and aldehydes/ketones were developed. Et3B promoted the generation of the potently reactive bridgehead radical from the O,Te-acetal of the
Application of α-alkoxy bridgehead radical for coupling of oxygenated carbocycles
Urabe, Daisuke,Yamaguchi, Hiroki,Inoue, Masayuki
, p. 4778 - 4781 (2011/11/12)
A new coupling methodology for assembly of highly oxygenated carbocycles was developed. An α-alkoxy bridgehead radical was employed as the key reactive intermediate due to its potent reactivity, minimum steric interaction, and predestined stereochemical o
