1326775-56-7Relevant academic research and scientific papers
Fluorine in pheromones: Synthesis of fluorinated 12-dodecanolides as emerald ash borer pheromone mimetics
Zhang, Qingzhi,Teschers, Charlotte S.,Callejo, Ricardo,Yang, Mingyan,Wang, Mingan,Silk, Peter J.,Ryall, Krista,Roscoe, Lucas E.,Cordes, David B.,Slawin, Alexandra M.Z.,O'Hagan, David
, p. 2917 - 2922 (2019/04/30)
A series of five 12-dodecanolides have been synthesised containing CF2 groups at C5, C6, C7, C8 and in one case, a double substitution at C5 & C8, as a strategy to bias the conformational space accessed by these macrocycles, and to assess if th
First asymmetric total synthesis of aspergillide D
Jena, Bighnanshu K.,Reddy, G. Sudhakar,Mohapatra, Debendra K.
, p. 1863 - 1871 (2017/03/09)
The first asymmetric total synthesis of a 16-membered macrolide, aspergillide D, is described. The chiral centers of the acid are derived from d-ribose and the alcohol subunit from 1,8-octane diol through Sharpless kinetic resolution, respectively. The other key reactions include Yamaguchi esterification, ring-closing metathesis reaction, and Shiina macrolactonization to construct the fully functionalized macrocycle.
Total synthesis of antifungal gamahonolide A
Sabitha, Gowravaram,Reddy, K. Purushotham,Reddy, S. Purushotham,Yadav
, p. 3227 - 3228 (2014/06/09)
The first stereoselective total synthesis of gamahonolide A (1) has been accomplished using aminoxylation, Keck allylation, and ring-closing metathesis (RCM) reactions as key steps.
METHOD FOR PRODUCING 18F-LABELED COMPOUND AND HIGH MOLECULAR COMPOUND TO BE USED IN THE METHOD
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, (2013/02/28)
The present invention aims at solving the problems of conventional methods for producing an 18F-labeled compound, that is, the problem of purification of a compound in a liquid phase synthesis method and the problem of an insufficient yield due
{1,6}-transannular catalytic asymmetric Gosteli-Claisen rearrangement
Jaschinski, Tobias,Hiersemann, Martin
supporting information; experimental part, p. 4114 - 4117 (2012/10/08)
The first uncatalyzed and [Cu(R-box)L2](SbF6) 2-catalyzed {1,6}-transannular Gosteli-Claisen rearrangement of cyclic 2-alkoxycarbonyl-substituted allyl vinyl ethers to afford medium- and large-sized carbacycles is disclosed.
