132769-61-0

Basic information

• Product Name: 3-phenyl-pent-4-ene nitrile
• Synonyms: 3-phenyl-pent-4-ene nitrile
• CAS NO: 132769-61-0
• Molecular Weight: 157.215
• Mol File: 132769-61-0.mol

Chemical Properties

• CAS DataBase Reference: 3-phenyl-pent-4-ene nitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 3-phenyl-pent-4-ene nitrile(132769-61-0)
• EPA Substance Registry System: 3-phenyl-pent-4-ene nitrile(132769-61-0)

Safety Data

• Hazardous Substances Data: 132769-61-0(Hazardous Substances Data)

Upstream product

• 1087162-37-5 methyl 2-cyano-3-phenylpent-4-enoate 

Downstream Products

• 918149-64-1 (S)-(-)-3-phenyl-4-pentenamide 
• 209900-64-1 (S)-3-phenyl-4-pentenoic acid 
• 675855-26-2 (R)-(+)-3-phenyl-4-pentenoic acid 
• 66859-48-1 (R)-(-)-4-amino-2-phenyl-butyric acid hydrochloride 
• 930273-65-7 (R)-N-allyl-N-benzyl-3-phenyl-4-pentenamide 
• 918149-86-7 (S)-(+)-N-allyl-N-benzyl-3-phenyl-4-pentenamide 
• 918149-84-5 (R)-(-)-4-benzoylamino-2-phenyl-butyric acid 
• 918149-83-4 (S)-(+)-N-(3-phenyl-pent-4-enyl)-benzamide 

Relevant articles and documents

Synthesis of Chiral Homoallylic Nitriles by Iridium-Catalyzed Allylation of Cyanoacetates

A synthesis of chiral homoallylic nitriles by the iridium-catalyzed allylation of cyanoacetates followed by Krapcho demethoxycarbonylation has been developed. A wide range of homoallylic nitriles were obtained with a high enantioselectivity (>95-99% ee). These compounds are useful chiral building blocks because further synthetic elaboration starting from a nitrile or terminal alkene is possible.

A new method for the generation and capture of iminyl radicals

Iminyl radicals can be generated from ketoxime esters and captured by an internal olefin; the sequence may be terminated in a variety of ways depending on the nature of the ensuing carbon radical and the added external trap.