13279-84-0Relevant articles and documents
Mechanism of the metathesis between carbon tetrachloride and (η1-allyl)iron complexes. A radical chain reaction of overall five-thirds order
Lee, Mei-Tsu,Waterman, Paul S.,Magnuson, Roy H.,Meirowitz, Randy E.,Prock, Alfred,Giering, Warren P.
, p. 2146 - 2149 (2008/10/08)
Chemical, kinetic, and stereochemical studies of the metatheses between CCl4 and η-CpFe(CO)2CH2CH=CR2 (R = H, Me) show that the reaction proceeds via a radical chain mechanism that involves the generation of the initiating radicals by a prequilibrium homolysis of the iron-allyl bond in the starting material. The ultimate product is formed by an SH2′ reaction between ?CCl3 and η-CpFe(CO)2CH2CH=CR2. The reaction follows a rate law with an unusual 5/3 total order: rate = kobsd[η-CpFe(CO)2CH2CH= CH2][CCl4]2/3.
REACTION OF ALLYL HALIDES WITH HALOFORMS AND ALKALI UNDER THE CONDITIONS OF INTERPHASE CATALYSIS
Mandel'shtam, T. V.,Kharicheva, E. M.,Labeish, N. N.,Kostikov, R. R.
, p. 2143 - 2148 (2007/10/02)
The reaction of allyl halides with haloforms and alkali in the presence of interphase transfer catalysts gives cyclopropanes and 4,4,4-trihalogeno-1-butenes.The latter are formed by nucleophilic substitution of the halogen in the allyl halide by the trihalogenomethyl anion.
