132799-06-5

Basic information

• Product Name: [3-((2R,3R,4S,5R,6S)-5-Benzyloxy-3,4-dihydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-propyl]-carbamic acid benzyl ester
• CAS NO: 132799-06-5
• Molecular Weight: 445.513
• Mol File: 132799-06-5.mol

Chemical Properties

• CAS DataBase Reference: [3-((2R,3R,4S,5R,6S)-5-Benzyloxy-3,4-dihydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-propyl]-carbamic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [3-((2R,3R,4S,5R,6S)-5-Benzyloxy-3,4-dihydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-propyl]-carbamic acid benzyl ester(132799-06-5)
• EPA Substance Registry System: [3-((2R,3R,4S,5R,6S)-5-Benzyloxy-3,4-dihydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-propyl]-carbamic acid benzyl ester(132799-06-5)

Safety Data

• Hazardous Substances Data: 132799-06-5(Hazardous Substances Data)

Upstream product

• 34637-22-4 3-[(N-benzyloxycarbonyl)amino]propanol 
• 132799-05-4 3-N-benzyloxycarbonylaminopropyl 2,3-di-O-acetyl-4-O-benzyl-α-L-rhamnopyranoside 

Downstream Products

• 212199-04-7 3-N-benzyloxycarbonylaminopropyl (3,4,6-tri-O-acetyl-2-O-allyl-α-D-galactopyranosyl)-(1-3)-(2,4,6-tri-O-benzyl-α-D-glucopyranosyl)-(1-3)-2-O-acetyl-4-O-benzyl-α-L-rhamnopyranoside 
• 212199-05-8 C₆₅H₇₇NO₂₁ 
• 212199-02-5 3-N-benzyloxycarbonylaminopropyl (3-O-allyl-2,4-6-tri-O-benzyl-α-D-glucopyranosyl)-(1-3)-2-O-acetyl-4-O-benzyl-α-L-rhamnopyranoside 
• 212199-03-6 3-N-benzyloxycarbonylaminopropyl (2,4,6-tri-O-benzyl-α-D-glucopyranosyl)-(1-3)-2-O-acetyl-4-O-benzyl-α-L-rhamnopyranoside 
• 212199-01-4 Acetic acid (2R,3R,4R,5R,6S)-5-benzyloxy-2-(3-benzyloxycarbonylamino-propoxy)-4-hydroxy-6-methyl-tetrahydro-pyran-3-yl ester 

Relevant articles and documents

Synthesis of four spacer-containing 'tetrasaccharides' that represent four possible repeating units of the capsular polysaccharide of Streptococcus pneumoniae type 6B

In the framework of studies towards oligosaccharide-conjugate based vaccines against Streptococcus pneumoniae, the synthesis is reported of four spacer-containing 'tetrasaccharides' that each can be conceived as representing a repeating unit of the capsular polysaccharide of S. pneumoniae serotype 6B, namely, 3-aminopropyl D-ribityl-(5 → hydrogen phosphate → 2)- α-D-galactopyranosyl-(1 → 3)-α-D-glucopyranosyl-(1 → 3)-α-L- rhamnopyranoside, 3-aminopropyl α-L-rhamnopyranosyl-(1 → 4)-D-ribityl-(5 → hydrogen phosphate → 2)-α-D-galactopyranosyl-(1 → 3)-α-D-glucopyranoside, 3-aminopropyl α-D-glucopyranosyl-(1 → 3)-α-L-rhamnopyranosyl-(1 → 4)-D- ribityl-(5 → hydrogen phosphate → 2)-α-D-galactopyranoside, and α-D- galactopyranosyl-(1 → 3)-α-D-glucopyranosyl-(1 → 3)-α-L-rhamnopyranosyl- (1 → 4)-5-O-(3-aminopropyl hydrogen phosphate)-D-ribitol. Phosphorylations were carried out using the H-phosphonate method.