132969-68-7

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 496035-49-5 methyl (2R,3S,4S)-2,4-dimethyl-3-hydroxy-5-(4-methoxybenzyloxy)pentanoate 
• 132969-64-3 tert-Butyl-[(1S,2S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2-methyl-propoxy]-dimethyl-silane 
• 132969-67-6 (1S,4S,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-4,6-dimethyl-1-[3-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-heptan-1-ol 
• 132969-66-5 (4S,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-4,6-dimethyl-1-[3-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-heptan-1-one 
• 133007-95-1 (2S,3R,4S)-5-[(4-methoxybenzyl)oxy]-2,4-dimethylpentane-1,3-diol 

Downstream Products

• 132969-70-1 (2R,8S,9R,10S,13S)-9-(tert-Butyl-dimethyl-silanyloxy)-7-hydroxy-13-methoxy-1-(4-methoxy-benzyloxy)-2,4,4,8,10-pentamethyl-13-[3-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-tridecan-5-one 
• 132969-59-6 (2R,3R,4S,7S)-3-(tert-Butyl-dimethyl-silanyloxy)-7-methoxy-2,4-dimethyl-7-[3-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-heptanal 

Relevant academic research and scientific papers

Expeditious synthesis of a key C9-C21 subunit of the aplysiatoxins and oscillatoxins

The C9-C21 portion of the aplysiatoxin/oscillatoxin bluegreen algal metabolites was synthesized as the 9-aldehyde bearing a tert-butyldimethylsilyl ether group on the C11 hydroxyl and a trimethylsilylethoxymethyl ether gro