133004-97-4

Upstream product

• 13720-12-2 4-(2',2'-Dimethyl-6'-methylidenecyclohexyl)butan-2-one 
• 132912-33-5 <3-(3-Furyl)propyl>triphenylphosphonium Bromide 
• 95452-03-2 3-(2',2'-dimethyl-6'-methylidenecyclohexyl)propionic acid 
• 128671-55-6 3-<3-(Tetrahydropyran-2-yloxy)propyl>furan 
• 132912-31-3 2-(3'-Furyl)-2-<2-(tetrahydropyran-2-yloxy)ethyl>-1,3-dithiane 
• 88214-43-1 1-<2'-(p-Toluenesulfonyl)ethyl>-2-methylene-6,6-dimethylcyclohexane 
• 132912-38-0 1-<2'-(p-Anisyldiphenylmethoxy)ethyl>-2-oxo-6,6-dimethylcyclohexane 
• 132912-39-1 1-<2'-(p-Anisyldiphenylmethoxy)ethyl>-2-methylene-6,6-dimethylcyclohexane 
• 132912-37-9 1-<2'-(p-Anisyldiphenylmethoxy)ethyl>-2-hydroxy-6,6-dimethylcyclohexane 
• 132912-36-8 2-(3',3'-Dimethyl-1'-hydroxycyclohexyl)ethanol 
• 98126-48-8 3-(3-furyl)-1-bromopropane 
• 56859-92-8 3-(3-furanyl)propan-1-ol 
• 57074-03-0 2-allyl-3,3-dimethylcyclohexan-1-one 
• 84078-59-1 2-(2'-Methylene-6',6'-dimethylcyclohexyl)ethanol 

Relevant academic research and scientific papers

Total Synthesis of Dehydroambliol-A and Its Unnatural Z Isomer

Convergent total syntheses of dehydroambliol-A (1a), its unnatural Z isomer 1b, and ambliofuran (2) are described.The syntheses utilized 2-(3'-furyl)-1,3-dithiane (6) as a common intermediate.Analysis of their proton and carbon magnetic resonance spectra confirm that in the natural product dehydroambliol-A and in synthetic dehydroambliol-A the Δ7-bond possesses the E geometry, while in the unnatural isomer of dehydroambliol-A, the Δ7-bond is of the Z configuration.