57074-03-0

Basic information

• Product Name: Cyclohexanone, 3,3-dimethyl-2-(2-propenyl)-
• CAS NO: 57074-03-0
• Molecular Formula: C11H18O
• Molecular Weight: 166.263
• Mol File: 57074-03-0.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 3,3-dimethyl-2-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 3,3-dimethyl-2-(2-propenyl)-(57074-03-0)
• EPA Substance Registry System: Cyclohexanone, 3,3-dimethyl-2-(2-propenyl)-(57074-03-0)

Safety Data

• Hazardous Substances Data: 57074-03-0(Hazardous Substances Data)

Upstream product

• 1193-18-6 3-methylcyclohexen-2-one 
• 75-16-1 methylmagnesium bromide 
• 106-95-6 allyl bromide 
• 95578-22-6 ethyl 3-allyl-2-methyl-4-oxocyclohex-2-ene-1-carboxylate 
• 487-51-4 4-carbethoxy-3-methyl-2-cyclohexen-1-one 
• 556-56-9 allyl iodid 
• 61175-92-6 3,3-dimethyl-1-<(trimethylsilyl)oxy>cyclohex-1-ene 
• 56745-18-7 2-allyl-3-bromocyclohex-2-en-1-one 
• 71135-95-0 methyl 2,2-dimethyl-6-oxocyclohexanecarboxylate 
• 35490-07-4 methyl 2-methyl-4-oxocyclohex-2-enecarboxylate 
• 866464-95-1 methyl 3-allyl-2-methyl-4-oxocyclohex-2-ene-carboxylate 
• 17605-08-2 2-allyl-3-methyl-2-cyclohexen-1-one 
• 917-54-4 methyllithium 
• 2979-19-3 3,3-dimethylcyclohexanone 

Downstream Products

• 15356-74-8 (+/-)-dihydroactinidiolide 
• 70902-31-7 (E)-Dehydroambliol-A 
• 133004-97-4 (Z)-Dehydroambliol-A 
• 132912-38-0 1-<2'-(p-Anisyldiphenylmethoxy)ethyl>-2-oxo-6,6-dimethylcyclohexane 
• 132912-39-1 1-<2'-(p-Anisyldiphenylmethoxy)ethyl>-2-methylene-6,6-dimethylcyclohexane 
• 132912-37-9 1-<2'-(p-Anisyldiphenylmethoxy)ethyl>-2-hydroxy-6,6-dimethylcyclohexane 
• 88214-43-1 1-<2'-(p-Toluenesulfonyl)ethyl>-2-methylene-6,6-dimethylcyclohexane 
• 132912-42-6 3-(2,2-Dimethyl-6-methylene-cyclohexyl)-1-methyl-propylideneamine 
• 95452-03-2 3-(2',2'-dimethyl-6'-methylidenecyclohexyl)propionic acid 
• 13720-12-2 4-(2',2'-Dimethyl-6'-methylidenecyclohexyl)butan-2-one 
• 84078-59-1 2-(2'-Methylene-6',6'-dimethylcyclohexyl)ethanol 
• 132912-40-4 1-(2'-Cyanoethyl)-2-methylene-6,6-dimethylcyclohexane 

Relevant articles and documents

Reductive Radical Annulation Strategy toward Bicyclo[3.2.1]octanes: Synthesis of ent-Kaurane and Beyerane Diterpenoids

Here we report a general [3 + 2] radical annulation that allows the facile construction of bicyclo[3.2.1]octane motifs in ent-kaurane- and beyerane-type diterpenoids. This radical annulation is difficult to control but was realized by harnessing an unprecedented and counterintuitive effect of TEMPO. Eleven natural products with a wide array of oxidation states are easily prepared, demonstrating the powerful utility of this straightforward synthetic strategy.

A concomitant allylic azide rearrangement/intramolecular azide-alkyne cycloaddition sequence

An intramolecular Huisgen cycloaddition of an interconverting set of isomeric allylic azides with alkynes affords substituted triazoles in high yield. The stereoisomeric vinyl-substituted triazoloxazines formed depend on the rate of cycloaddition of the d

A concise approach to the polycyclic scaffold of frondosin D

(Chemical Equation Presented) In a study directed at developing a concise approach to the polycyclic core of frondosin D, a Stille-Heck sequence has been identified that gives direct access to the trimethylbicyclo [5.4.0]undecane ring system common to all frondosins.