13307-64-7Relevant academic research and scientific papers
Copper-Catalyzed Synthesis of gem-Bisarylthio Enamines under Redox-Neutral Conditions
Ni, Jiabin,Mao, Xiaokang,Zhang, Ao
supporting information, p. 2004 - 2008 (2019/03/21)
An efficient approach for the construction of gem-bisarylthio enamines via coupling of oxime acetates with diaryl disulfides is developed. This process involved copper-catalyzed N?O/S?S bond cleavages and formation of two new C?S bonds. A broad range of s
Nucleophilic fluoromethylation of aldehydes with fluorobis(phenylsulfonyl) methane: The importance of strong Li-O coordination and fluorine substitution for C-C bond formation
Shen, Xiao,Zhang, Laijun,Zhao, Yanchuan,Zhu, Lingui,Li, Guangyu,Hu, Jinbo
supporting information; experimental part, p. 2588 - 2592 (2011/04/25)
The tighter, the better! Fluorobis(phenylsulfonyl)methane reacts readily with aldehydes to give addition products in excellent yields (see scheme; LiHMDS=lithium hexamethyldisilazide), which is in sharp contrast to previous findings. Both strong Li-O coordination at low temperature and fluorine substitution play important roles in successful C-C bond formation. Copyright
Mechanistic Insight into Allylmetal-Thioacetal Reactions Employing 2-Acetoxy-2-phenylacetaldehyde Thioacetals
Sato, Tsuneo,Otera, Junzo,Nozaki, Hitosi
, p. 6116 - 6121 (2007/10/02)
The mechanism of allyl-metal-thioacetal reactions has been investigated by using 2-acetoxy-2-phenylacetaldehyde thioacetals in the presence of trimethylsilyl triflate.The results unambiguously revealed the occurence of both SN1- and SN/su
